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含氟人工唾液对选择性激光熔积钴铬合金耐腐蚀性的影响 被引量:1

Effects of different fluorine-containing oral artificial saliva solution on anti-corrosion behavior of selective laser melting cobalt-chromium alloy
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摘要 目的观察含氟人工唾液对选择性激光熔积技术(SLM)制作的钴铬合金耐腐蚀性的影响。方法将具有相同成分的钴铬合金粉末和金属块,分别运用SLM技术(SLM组)和铸造工艺(对照组)制作试件,每组40个。分别在pH为5.0和2.5以及模拟口腔含氟0、0.05%、0.10%和0.20%的条件下,将试件置于Fusayam人工唾液中浸泡24 h。采用极化曲线Tafel外延法求得两组试样的极化阻力Rp值,比较两组试件的耐腐蚀性。结果 pH值为5.0时,在含氟0和0.05%的条件下,两组间Rp值比较差异无统计学意义(P>0.05);而在含氟0.1%和0.2%的条件下,SLM组的Rp值显著大于对照组(P<0.05)。当pH为2.5时,在含氟0、0.05%、0.10%和0.20%的条件下,SLM组的Rp值均显著大于对照组(P<0.05)。结论氟化物能影响钴铬合金的耐腐蚀性能,SLM钴铬合金的耐腐蚀性优于铸造钴铬合金。 Objective To evaluate the effects of different fluoride-containing artificial saliva solution on the corrosion of the dental cobalt-chromium (Co-Cr) alloy fabricated by selective laser melting (SLM). Methods The study involved two groups, each group has 40 cylinder specimens and all specimens were fabricated by the same Co-Cr alloy. One group adopted SLM, while the other group used the cast method. Under conditions of two different pHs (2.5 and 5.0) and four different fluoride-containing artificial saliva solution concentration (0, 0. 05%, 0. 1%, and 0.2% ), polarization curve tests were performed to compare the anti-corrosion ability of two groups. Results For pH of 5. 0 (fluoride- containing artificial saliva solution concentrations were 0 and 0. 05% ), differences of Rp values between two groups were not statistically significant (P 〉 0. 05). For pH of 5. 0 (fluoride-containing artificial saliva solution concentration were 0. 1% and 0. 2% ) and pH of 2.5 (fluoride-containing artificial saliva solution concentration were 0, 0. 05%, 0. 1%, and 0. 2% ), the Rp value of SLM specimens were significantly higher than those of the cast ones (P 〈 0. 05). Conclusion Fluorine can affect the anti-corrosion ability of Co-Cr alloy. SLM specimens exhibited a significantly better anti-corrosion ability than cast ones.
出处 《上海交通大学学报(医学版)》 CAS CSCD 北大核心 2014年第3期314-317,328,共5页 Journal of Shanghai Jiao tong University:Medical Science
基金 上海市科委资助项目(12441903001 13140902701)~~
关键词 选择性激光熔积技术 钴铬合金 氟化物 耐腐蚀性 selective laser melting Cobalt-chromium alloy fluoride anti-corrosion behavior
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