摘要
The dynamic interfacial tensions between hydrocarbons and solutions of surfactants having different hydrophilic- lipophilic ability are measured.The effects of ionic strength and alkyl chain carbon- number on dynamic interfacial tensions are also studied.It is found that adsorption- desorption barriers are connected with the hydrophilic- lipophilic ability of surfactants.There exists a large or small adsorption- desorption barrier to the transfer of surfactant having strong hydrophilic or lipophilic ability from water to oil.The influences of ionic strength and alkyl chain carbon- number on adsorption- desorption barriers are discussed.
The dynamic interfacial tensions between hydrocarbons and solutions of surfactants having different hydrophilic-lipophilic ability are measured. The effects of ionic strength and alkyl chain carbon-number on dynamic interfacial tensions are also studied, It is found that adsorption-desorption barriers are connected with the hydrophilic-lipophilic ability of surfactants, There exists a large or small adsorption-desorption barrier to the transfer of surfactant having strong hydrophilic or lipophilic ability from water to oil, The influences of ionic strength and alkyl chain carbon-number on adsorption-desorption barriers are discussed.
出处
《物理化学学报》
SCIE
CAS
CSCD
北大核心
2001年第1期62-65,共4页
Acta Physico-Chimica Sinica
基金
国家重点研究基础规划资助