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表面活性剂亲水-亲油能力对动态界面张力的影响 被引量:44

Effect of Hydrophilic- Lipophilic Ability of Surfactant on Dynamic Interfacial Tensions
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摘要 The dynamic interfacial tensions between hydrocarbons and solutions of surfactants having different hydrophilic- lipophilic ability are measured.The effects of ionic strength and alkyl chain carbon- number on dynamic interfacial tensions are also studied.It is found that adsorption- desorption barriers are connected with the hydrophilic- lipophilic ability of surfactants.There exists a large or small adsorption- desorption barrier to the transfer of surfactant having strong hydrophilic or lipophilic ability from water to oil.The influences of ionic strength and alkyl chain carbon- number on adsorption- desorption barriers are discussed. The dynamic interfacial tensions between hydrocarbons and solutions of surfactants having different hydrophilic-lipophilic ability are measured. The effects of ionic strength and alkyl chain carbon-number on dynamic interfacial tensions are also studied, It is found that adsorption-desorption barriers are connected with the hydrophilic-lipophilic ability of surfactants, There exists a large or small adsorption-desorption barrier to the transfer of surfactant having strong hydrophilic or lipophilic ability from water to oil, The influences of ionic strength and alkyl chain carbon-number on adsorption-desorption barriers are discussed.
出处 《物理化学学报》 SCIE CAS CSCD 北大核心 2001年第1期62-65,共4页 Acta Physico-Chimica Sinica
基金 国家重点研究基础规划资助
关键词 动态界面张力 正态烷烃 石油磺酸盐 吸附-脱附位垒 亲水-亲油能力 表面活性剂 化学驱油 dynamic interfacial tension adsorption-desorption barrier hydrophilic-lipophilic ability
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参考文献1

  • 1Chan K S,J Dispersion Sci Technol,1980年,1卷,55页

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