摘要
本文通过改变两种石油磺酸盐的混合比例,配制出碳数最低值不同的一系列混合表面活性剂溶液作为标尺,考察了几种有机酸、十八醇、Span60 及两种卟啉( OEP和ETIO) 对正癸烷模拟油的EACN 值及油水界面张力的影响。
A series of standard aqueuos solutions of petroleum sulfonates LH and La in various proportions with salinity 0.171 mol/L NaCl is used as the aqueous phase and different normal alkanes(C 5-C 14 ,C 10 in most cases)-as the oil phase modelling the crude oil in EOR studies. Some saturated aliphatic mormal acids(C 8,C 10 ,C 12 ,C 18 ), oleic acid, cyclohexyl carboxylic acid, and two porphyrins(OEP and ETIO) are added into the alkanes and their EACN values are determined using the criteria rules as minimum ACN value for the standard aqueous phase which gives the lowest stable value of transient interfacial tension with the alkane. The transient interfacial tension is also studied. The results obtained are discussed and reasoned.
出处
《油田化学》
CAS
CSCD
北大核心
1999年第4期356-361,共6页
Oilfield Chemistry
基金
国家攀登(B) 计划"复合驱强化采油技术中重大基础性研究"项目!( 项目编号8533) 资助
关键词
界面张力
化学驱油
表面活性剂
驱油剂
Equivalent Alkane Carbon Number(EACN)
Modelling Crude Oil
Surface Active Substances
Normal Alkanes
Mixed Petroleum Sulfonates
Dynamic Interfacial Tension