摘要
为高效利用海生节肢类废弃物,采用化学预处理结合超声法处理废弃蟹壳,从中分离制备α-甲壳素纳米纤维(α-NCF),同时制备了甲壳素纳米纤维气凝胶(NCA)材料。采用场发射扫描电镜(FE-SEM)、X射线衍射仪(XRD)、傅里叶变换红外光谱仪(FTIR)和BET比表面积测定,对制备的α-NCF和NCA的形态特征、结晶特性、化学结构和比表面积进行了测试表征。结果表明,制备的α-NCF为丝状交联结构,直径约为20 nm;FTIR表明化学预处理可有效脱除蟹壳中的蛋白质和矿物质;制备的α-NCF的结晶度为85.4%,具有较好的结晶性;制备的NCA的比表面积为133 m2/g,且柔性可折叠。研究结果为高效开发利用海洋生物质资源提供了一定的研究思路和理论指导。
To efficiently utilize waste marine arthropod materials, α-chitin nanoflbers （α-NCF） and a-chitin aerogel （NCA） were prepared from discarded crab shells via ultrasonic method combined with pre-chemical treatment. The morphological features, crystalline characteristics, chemical structures, and specific surface area of the as-prepared materials were characterized by field emission electron microscopy （FE-SEM）, X-ray diffraction （XRD）, fourier transform infrared spectroscopy （FTIR） and BET method. The results showed that the diameter of the obtained chitin nanofibers was evenly about 20 nm with cross-linked thread-like structures. It was confirmed from FTIR spectra that the natural chitin/protein/mineral composites in the crab shells have been completely removed through the chemical treatment. The prepared α-NCF possess a high erystallinity of 85.4%. Meanwhile, the freezing-dried chitin aerogel has flexibility as well as a relatively high BET of 133 m2/g.
出处
《科技导报》
CAS
CSCD
北大核心
2014年第4期61-64,共4页
Science & Technology Review
基金
国家自然科学基金面上项目(31270590)
<科技导报>"博士生创新研究资助计划"项目(kjdb2012006)
中国博士后科学基金资助项目(2013M540263)
关键词
蟹壳
甲壳素
纳米纤维
超声法
气凝胶
crab shell
chitin
nanofiber
ultrasonic method
aerogel
