摘要
文章建立了液相色谱-串联四级杆质谱仪同时测定土壤中四溴双酚A及3种六溴环十二烷同分异构体的分析方法.土壤样品经快速溶剂仪萃取,全自动凝胶净化系统净化后,使用液相色谱-串联四级杆质谱仪,负离子电喷雾多反应监测模式监测,内标法定量分析.结果表明,土壤中四溴双酚A、α-六溴环十二烷、β-六溴环十二烷和γ-六溴环十二烷的检出限为0.1 ～1.2 p∥g,加标回收率为81.8％～113％,相对标准偏差小于10％.该方法分析时间短,灵敏度高,操作简单,对电子固废拆解场地中的179个土壤样品进行分析,取得满意结果.
In this study,an analytical method to the determinate TBBPA,α-HBCD,β-HBCD and γ-HBCD in soil,was developed by liquid chromatography-tandem mass spectrometry.The soil samples were extracted by ASE,further purified using GPC,and detected by an electrospray ionization tandem mass spectrometry in the multiple-reaction-monitoring negative mode.And the quantitative results were calculated by the internal standard methods.The results showed that the limits of detection （LODs） of TBBPA,α-HBCD,β-HBCD,and γ-HBCD ranged from 0.1 pg/g to 1.2 pg/g,and the recoveries were from 81.8% to 113%,the relative standard deviations（RSDs） were less than 10%.The method was simple,sensitive,and need short time to operate.Also,the method was applied for analysis to 179 soil samples which were collected from an electrical waste site,and satisfactory results was achieved.
出处
《中国环境监测》
CAS
CSCD
北大核心
2013年第6期108-112,共5页
Environmental Monitoring in China
