摘要
介绍了可以实现活性聚合的ATRP、RATRP、AGET ATRP和ARGET ATRP 4种原子转移自由基聚合的机理,综述了原子转移自由基聚合技术在合成两亲性嵌段共聚物、接枝聚合物和星型共聚物等中的研究进展。
The mechanisms for four kinds of atom transfer radical polymerizations such as ATRP, RATRP, AGET ATRP and ARGET ATRP which can realize the living polymerization are introduced. The research progress of the atom transfer radical polymerization technique in synthesis of amphiphatic block copolymer, graft polymer, star-shape copolymer, and so on is reviewed.
出处
《化学推进剂与高分子材料》
CAS
2014年第1期32-36,共5页
Chemical Propellants & Polymeric Materials
关键词
原子转移自由基聚合(ATRP)
聚合机理
研究进展
atom transfer radical polymerization （ATRP）
amphiphatic block copolymer
graft polymer
star-shape copolymer
polymerization mechanism
research progress
