摘要
综述了胺存在下自由基聚合,包括含胺的过氧化二酰与芳叔胺氧化还原体系、有机过氧化氢物与芳叔胺或脂肪叔胺氧化还原体系、过硫酸盐与脂肪胺氧化还原体系和极性单体的胺光诱导电荷转移引发自由基聚合,以及活性/控制自由基聚合,主要为原子转移自由基研究的成果。
The polymerizations of vinyl monomers in the presence of amine including benzoyl peroxide-tertiary aromatic amine, organic peroxide-amine and persulfate sah-aliphatic amine redox initiation system as well as the photo-induced charge transfer polymerization of vinyl monomer as electron acceptor using amine as electron donor were reviewed. Living radical polymerization and some new initiation systems for atom transfer radical polymerization （ATRP） developed in our lab, including the C-C type compound as initiator in conjunction with Fe（Ⅲ）, Cu（ Ⅱ ） catalyst in reverse ATRP; the pseudo-halo transfer in normal ATRP using Cu（S2CNEt2） as catalyst or in reverse ATRP using Cu（S2CNEt2 ）C1 as catalyst; the in situ ATRP using S-S type compound tetraethyhhiuram disulfide （TD） as initiator and FeCl3 or CuBr2 as catalyst were briefly summarized.
出处
《高分子通报》
CAS
CSCD
2005年第4期23-34,共12页
Polymer Bulletin
基金
国家自然科学基金国家自然科学基金重大项目(批准号:9287008)
国家自然科学基金重点项目(批准号:29234093-1)
国家教委博士点基金(批准号:32750682)等的资助。
关键词
自由基聚合
胺
活性自由基
过氧化二酰
芳叔胺
氧化还原体系
原子转移
Amine-containing redox initiation system
Photo-induced charge transfer polymerization
Living radical polymerization
Atom transfer radical polymerization
Initiating polymerization mechanism
