摘要
合成了一种耐温抗盐表面活性剂,通过红外光谱分析了该表面活性剂的结构。将其与2500万分子量聚丙烯酰胺进行复配,考察了复配体系的表面、界面性能。研究结果表明:所合成的产物为目标产物;磺基甜菜碱表面活性剂的临界胶束浓度(cmc)为2.19×10^-3mol/L,临界胶束浓度下的表面张力(γcmc)为25.51mN/m;加入聚合物后临界胶束浓度变为4.09×10^-3mol/L,γcmc变为26.65mN/m;表面活性剂质量浓度在0.8—1.5g/L,可使胜利原油油水间的界面张力达到超低数量级(10^-3mN/m);聚合物的加入有利于乳状液的形成。
A heat resisting and salt tolerant surfactant is synthesized, and the structure is analyzed by Infrared (IR). The sulfobe- taine surfactant is compounded with 25 million molecular weight of polymer, the surface and interfacial properties of the compound sys- tem are investigated. The experimental resuhs indicate that the product is the target one, the critical micelle concentration of sulfobe- taine surfactant is 2. 19 × 10-3 tool/L, the surface tension (γcmc) is 25.51 mN/m; with the polymer added, the cmc become 4. 09 ×10-3 mol/L, and the Tome become 26. 65 mN/m; the mass concentration of surfactant is in the range of 0. 8 g/L to 1.5 g/L, the water/crude oil interfacial tension is arrived ultra low value 10-3 mN/m from Shengli oilfield. It is conductive to form the emulsion due to the poly- mer added.
出处
《化学工业与工程技术》
CAS
2013年第6期33-35,共3页
Journal of Chemical Industry & Engineering
基金
国家重大科技专项基金(2011ZX05011-004)资助项目
关键词
甜菜碱表面活性剂
表面张力
界面张力
乳化性能
Betaine surfactang
Surface tension
Interfacial tension
Emulsifying performance