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化学法沉积银岛膜上的表面增强拉曼散射(Ⅱ) 被引量:4

Surface Enhanced Raman Scattering of Malachite Green on Silver Film From Chemical Method ( Ⅱ)
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摘要 用化学法在抛光的石英玻璃片上沉积银岛膜,并在该膜上进行孔雀石绿分子的表面增强拉曼散射研究,着重考察了激发波长、电解质浓度以及酸度对SERS的影响。 We measured the surface enhanced Raman spectra (SERS) of the malachite green on silver film deposited on optic polished quartz slides by using chemical method. The effects of the excitation wavelength, electrolyte (NaCl) concentration and pH on the SERS were investigated. The results indicate that the relative intensities for some bands depended upon the excitation wavelength; Inorganic anion(Cl-) not only enhanced the SERS intensities, but also changed the relative intensities of the SERS sensitive bands; The SERS intensities increased with pH from 1-7 and reached maximum value at pH = 7, and then decreased. The possible origin for the phenomena was discussed.
出处 《高等学校化学学报》 SCIE EI CAS CSCD 北大核心 1991年第9期1225-1228,共4页 Chemical Journal of Chinese Universities
基金 国家自然科学基金
关键词 化学法 沉积 银岛膜 SERS 孔雀石绿 Surface enhanced raman scattering, Malachite green, Adsorption
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参考文献3

  • 1张建华,高等学校化学学报,1991年,12卷,1220页
  • 2段世铎,界面化学,1990年
  • 3Fan Ni,Anal Chem,1986年,58卷,3159页

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