摘要
合成了镉与2-[(邻羟苄叉)氨基]酚(H_2Sap)和吡啶配合物,Cd_2(C_(13)H_9No_2)_2(C_5H_5N)_6.测定其晶体属单针晶系,P2_1/c空间群,的配位构型为八面体.用红外、核磁、热分析等枝术进行了表征.
A complex of cadmium with 2-[(o-hydroxybenzylidene) amino] phenol (H2Sap) and pyri-dine Cd2(C13H9NO2)2(C5H5)6 was prepared. Its structure was determined. It is found that the crystal belongs to the monoclinic system with space group P21/c, and the unit cell parameters are:n=14. 006(3) A , b= 10. 362(1) A , c= 18. 435(2) A ,β=111.29(1)°,V= 2492. 77A3 M=1121.86, Z = 2, DI= 1.495g/cm3, μ=9. 023 cm-1, F(000) = 1136.The cadmium coordination configuration is octahedral. The properties of the complex have been characterized by IR, NMR, DTA and TG techniques.
出处
《高等学校化学学报》
SCIE
EI
CAS
CSCD
北大核心
1991年第2期165-168,共4页
Chemical Journal of Chinese Universities
关键词
镉
HaSap
吡啶
络合物
晶体结构
Cadmium, Coordination compound, Properties, Structure
