摘要
合成了镍(Ⅱ)与2-[(邻羟苄叉)胺基]酚的配合物。在吡啶中用蒸发的方法培养出单晶,测定其结构。晶体属四方晶系,空间群为 I4_1cd。晶胞参数:a=1.9773(2)nm,c=2.5092(3)nm;V=9.8103nm^3,M_r=507.24,Z=16,D_c=1.37g/cm^3,μ=8.24cm^(-1),F(000)=4224。
The coordination compound of Ni(Ⅱ)with 2-[(O-hydroxybenzylide- ne)amino] phenol was prepared.The monocrystal was cultured by means of vaporization in pyridine.It was found that the crystal belongs to the monoclinic system with space group Ⅰ_4_1cd.The unit cell parameters are: a=1.9773(2)nm,c=2.5092(3)nm,v=9.8103nm^3,Mr=507.24,z=16,Dc =1.37g/cm^3,μ=8.24cm^(-1),F(000)=4224.
出处
《山东大学学报（自然科学版）》
CSCD
1990年第3期362-367,共6页
Journal of Shandong University(Natural Science Edition)
关键词
镍
配合物
晶体结构
酚
吡啶
混合
Nickel
coordination compound
crystal structure
