期刊文献+

硫酸盐对不同侧链分子量聚羧酸减水剂分散性的影响 被引量:3

Influence of Sulfate on the Dispersity of Polycarboxylate Superplasticizer of Different Side Chain Molecular Weight
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摘要 通过测定Na2SO4和CaSO4·2H2O对掺侧链分子量不同的聚羧酸减水剂时水泥净浆流动度及砂浆扩展度的影响来表征硫酸盐对聚羧酸减水剂分散性的影响。结果发现:硫酸盐对聚羧酸减水剂的减水分散性能有不利影响;Na2SO4对聚羧酸减水剂分散性的负面影响较CaSO4·2H2O更显著;此外,侧链分子量较大的聚羧酸减水剂对Na2SO4更加敏感。 By measuring the effect of Na2SO4 and CaSO4· 2H2O on fluidity of cement paste and extension of cement mortar with polyearboxylate superplasticizers of different side chain molecular weight, a conclusion can be drawn that sulfates have negative effect on the water reducing performance of polycarboxylate superplasticizer. Compared with CaSO4 · 2H2O, Na2SO4 displayed a more pronounced negative effect on dispersity of polycarboxylate superplasticizer. What ‘s more, polycarboxylate superplasticizers with larger side chain molecular weight are more sensitive to sulfates.
出处 《硅酸盐通报》 CAS CSCD 北大核心 2013年第12期2578-2582,2594,共6页 Bulletin of the Chinese Ceramic Society
基金 国家自然科学基金项目(50972170) 国家自然科学基金重点项目(51132010)
关键词 硫酸盐 聚羧酸减水剂 分散性 sulfate polycarboxylate superplasticizer dispersity
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参考文献15

  • 1Carmel J, Marc-Andre S. Chemical admixture-cement interactions: phenomenology and physico-chemical concepts [ J]. Cement and Concrete Composites, 1998,20 (2-3) :87-101.
  • 2齐秀梅.水泥和矿物掺合料与减水剂相容性问题的研究[J].混凝土,2009(12):65-67. 被引量:4
  • 3于长江,陶成云.硫酸钠的掺量对混凝土坍落度的影响[J].低温建筑技术,2003,25(6):88-89. 被引量:5
  • 4Kumar S, Kameswara R. Effect of sulfates on the setting time of cement and strength of concrete [ J ]. Cement and Concrete Research, 1994,24(7 ) : 1237-1244.
  • 5Mukesh K, Narendra P S, Sanjay K S, et al. Combined effect of sodium sulphate and superplasticizer on the hydration of fly ash blended portland cement [ J ]. Material Research, 2010,13 ( 2 ) : 177-183.
  • 6Kazuo Y, Shoiehi O, Shunsuke H. Controlling of the adsorption and dispersing force of polycarboxylate-type superplasticizer by sulfate ion concentration in aqueous phase[ J]. Cement and Concrete Research,2001,31:375-383.
  • 7Claire G, Jean-Baptiste D, Zied S, et al. Surface and intercalation chemistry of polycarboxylate copolymers in eementitious systems [ J ]. Journal of the American Ceramic Society,2009,92( 11 ) :2471-2488.
  • 8韩松,阎培渝.硫酸盐对萘系减水剂与水泥相容性的影响[J].硅酸盐学报,2010,38(9):1765-1770. 被引量:35
  • 9Houst Y F, Bowen P, Perehe F, et al. Design and function of novel superplasticizers for more durable high performance concrete ( superplast project) [ J ]. Cement and Concrete Research,2008, (38) : 1197-1209.
  • 10Toyoharu N. Effect of chemical structure on steric stabilization of polycarboxylate-based superplasticizer [ J 1- Journal of Advanced Concrete Technology, 2006, ( 4 ) : 225-232.

二级参考文献18

  • 1瞿金东,彭家惠,陈明凤,张建新,万体智.减水剂吸附性能试验方法进展[J].混凝土,2004(9):27-28. 被引量:4
  • 2覃维祖.水泥——高效减水剂相容性及其检测研究[J].混凝土,1996(2):11-17. 被引量:58
  • 3阎培渝,王悦.利用正交试验方法研究普通硅酸盐水泥与高效减水剂的相容性[J].水泥技术,2006(1):31-34. 被引量:14
  • 4HOD W S,SHEINN A M M,TAM C T.The sandwich concept of construction with SCC[J].Cement and Concrete Research,2001(31) : 1377-1381.
  • 5HANEHARA S,YAMADA K.Interaction between cement and chemical admixture from the point of cement hydration,absorption behavionr of admixture,and paste theology[J].Cem Concr Res,1999,29:1159-1165.
  • 6JIANG Shiping,GIKIM B,AITEIN P C.Importance of adeqante soluble alkali content to ensure cement/superplasticizor compatibility[J].Cem Concr Res,1999,29:71-78.
  • 7BONEN D,SARKAR S L.The superplasticizer adsorption capacity of cement pastes,pore soluteion compositeon,and parameters affecting flow loss[J].Cem Concr Res,1995,25:1423-1434.
  • 8PRINCEA W,ESPAGNEA M,AITICIN P C.Ettringite formation:a crucial step in cement superplasticizer compatibility[J].Cem Concr Res,2003,33:635-641.
  • 9YAMADA K,OGAWA S,HANEHARA S.Controlling of the adsorption and dispersing force ofpolycarboxylate-type superplasticizer by sulfate ion concentration in aqueous phase[J].Cem Concr Res,2001,31:375-383.
  • 10NAKAAIMA Y,YAMADA K.The affect of the kind of calcium sulfate in cements on the dispersing ability of poly β-naphthalene sulfonate condensate superplasticizer[J].Cem Concr Res,2004,34:839-844.

共引文献44

同被引文献44

  • 1李崇智,冯乃谦,牛全林.聚羧酸系减水剂结构模型与高性能化分子设计[J].建筑材料学报,2004,7(2):194-201. 被引量:51
  • 2沈军,傅乐峰,冯中军,季春伟,王肖峰,郑柏存.聚醚基超塑化剂的合成及其性能研究[J].混凝土,2005(6):61-64. 被引量:21
  • 3刘治猛,罗远芳,刘煜平,等.新型聚羧酸类高效减水剂的合成与性能研究[J].化学建材,2004(4):15-18.
  • 4Aitcin P C ,Jolicoeur, C, MacGregor, J G. Superplasticizers : how they work and why they occasionally don t [ J ]. Concrete International, 1994,16 (5) :45-52.
  • 5Ramachandren V S, Bented J, Collepardi M M. Concrete admixtures handbook : Properties Seience and Technology [ M ]. New Jersey : Noyes Publications, 1995.
  • 6余铖.采用烯丙醇聚氧乙烯醚合成聚羧酸系高效减水剂及其性能研究[D].重庆:重庆大学学位论文,2008.
  • 7邹邵华.聚酯与聚醚型减水剂的合成和性能研究[D].北京:北京交通大学硕士学位论文,2010.
  • 8杨晓峰,熊卫峰.早强聚羧酸减水剂[P].中国:CNl02503227A,2012.
  • 9黄玉华,王志勇,黄海,等.聚羧酸减水剂的制备方法[P].中国:CNl01983975A,2011-3.
  • 10张建峰,王家丰,宋永良,等.一种具有优异保坍性能的多支剂及其制备方[P].中国:CNl0185132A,2010-10.

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