摘要
以 1 2 -钨 (钼 )磷杂多酸为掺杂剂 ,合成了聚N ,N -二甲基苯胺 ,并利用ICP、元素分析、循环伏安、红外光谱及室温固体电导率的测定等手段进行了表征 .结果表明 ,掺杂的PDMAn/PM12 的室温导电率约为1 2～ 1 3S/cm .
The poly N,N-dimethylaniline was synthesized from t he 12-molybdophosphoric acid and 12-tungstophosphoric acid used as a doping agent and N,N-dimethylaniline. Their structures and properties were characterized by I CP, elemental analysis, CV,IR, and conductivity measurement. The result showed t ha t the conductivity of [(DMAn) 6PM 12O 40 ] X reached 12～13 ?S/cm at room temperature.
出处
《湖北大学学报（自然科学版）》
CAS
2000年第3期270-273,共4页
Journal of Hubei University：Natural Science
基金
国家自然科学基金!( 2 99710 10 )
湖北省自然科学基金!( 99J0 66)资助课题
关键词
聚N
N-二甲基苯胺
掺杂剂
合成
钨磷杂多酸
poly N,N-dimethylaniline
heteropolyacid with Keggin structure
doping agent
chemical polymerization
conductivity
