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Photocatalytic Denitrogenation over Modified Waste FCC Catalyst

Photocatalytic Denitrogenation over Modified Waste FCC Catalyst
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摘要 The strontium modified waste FCC catalyst was prepared by magnetic stirring method and characterized by Xray diffractometry(XRD),UV-Vis diffuse reflectance spectrometry(DRS),X-ray photoelectron spectroscopy(XPS)and scanning electron microscopy(SEM).Meanwhile,its photocatalytic denitrogenation performance was evaluated in terms of its ability to degrade the N-containing simulation oil under visible light.A mixture of strontium nitrate solution(with a concentration of 0.5 mol/L)and waste FCC catalyst was calcined at 400℃for 5 h prior to taking part in the photocatalytic denitrogenation reaction.The test results showed that the photocatalytic degradation rate of pyridine contained in simulation oil in the presence of the strontium modified FCC catalyst could reach 92.0% under visible light irradiation for 2.5 h. The strontium modified waste FCC catalyst was prepared by magnetic stirring method and characterized by Xray diffractometry(XRD), UV-Vis diffuse reflectance spectrometry(DRS), X-ray photoelectron spectroscopy(XPS)and scanning electron microscopy(SEM).Meanwhile, its photocatalytic denitrogenation performance was evaluated in terms of its ability to degrade the N-containing simulation oil under visible light.A mixture of strontium nitrate solution(with a concentration of 0.5 mol/L)and waste FCC catalyst was calcined at 400 ℃ for 5 h prior to taking part in the photocatalytic denitrogenation reaction.The test results showed that the photocatalytic degradation rate of pyridine contained in simulation oil in the presence of the strontium modified FCC catalyst could reach 92.0% under visible light irradiation for 2.5 h.
出处 《China Petroleum Processing & Petrochemical Technology》 SCIE CAS 2013年第3期33-37,共5页 中国炼油与石油化工(英文版)
基金 financially supported by the Science and Technology Project of Fujian Province(No.CE0015) the Ningde Normal University Project on Serving the Western Coast to the TW Strait(No.2010H103) the National-level College Students’ Innovative Entrepreneurial Training Plan Project of Fujian Normal University(Nos.201210394005 and 201310394015)
关键词 waste FCC catalyst PHOTOCATALYSIS denitrogenation 脱氮性能 FCC废催化剂 光催化 催化裂化催化剂 X-射线光电子能谱 扫描电子显微镜 可见光照射 改良
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