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介孔材料SBA-15固定化脂肪酶的研究进展 被引量:4

Research Progress of Immobilization of Lipase on Molecular Sieve Mesoporous Silica SBA-15
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摘要 介孔材料由于其孔道分布有序且孔径均匀等优点而在固定化酶催化领域引起人们的广泛关注。本文综述了新型介孔材料SBA-15对脂肪酶固定化的研究进展。总结了SBA-15的孔径大小、形貌及等电点等因素对脂肪酶固定化的影响。归纳了SBA-15上三种不同固定化方法的优缺点,并介绍了SBA-15固定化脂肪酶在手性拆分、酯水解、酯合成及转酯化反应等领域的应用。最后提出SBA-15固定化脂肪酶在发展过程中存在的问题以及今后的发展趋势。 Due to the merit of average pore diameter and ordered pore arrangement,more and more attention has been paid to the molecular sieve mesoporous silica SBA-15.The recent research progress of lipase immobilization on SBA-15 mesoporous materials are reviewed in this paper.The factors that influence the immobilization of lipase on mesoporous materials are investigated in detail.At last,the applications and the prospects of the immobilization of lipase on SBA-15 are also presented.
作者 黄卓楠
出处 《硅酸盐通报》 CAS CSCD 北大核心 2013年第7期1311-1317,共7页 Bulletin of the Chinese Ceramic Society
基金 陕西省宝鸡文理学院院级项目(ZK11154)资助
关键词 SBA-15 脂肪酶 固定化 催化活性 molecular sieve mesoporous silica SBA-15 lipase immobilization catalytic activities
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  • 1张微,徐恒泳,毕亚东,李文钊.介孔分子筛SBA-15的改性研究进展[J].化工进展,2007,26(2):152-157. 被引量:28
  • 2曾淑华,杨江科,闫云君.固定化脂肪酶性质及其应用研究[J].生物加工过程,2007,5(1):45-49. 被引量:13
  • 3薛屏,严祥辉.CS-MCM-48复合载体固定化脂肪酶催化苯乙酮一锅法还原转酯化拆分反应[J].应用化学,2007,24(3):245-250. 被引量:3
  • 4Ajitha S,Sugunan S.Tuning mesoporous molecular sieve SBA-15 for the immobilization of alpha-amylase[J].J.Porous.Mat.,2010,17:341-349.
  • 5Yang C Z,Huang M H.Formation of arrays of gallium nitride nanorods within mesoporous silica SBA-15[J].J.Phys.Chem.B,2005,109(38):17842-17847.
  • 6Ryoo R,Joo S H,Jun S.Synthesis of highly ordered carbon molecular sieves via template-mediated structural transformation[J].J.Phy.Chem.B,1999,103:7743-7746.
  • 7Ryoo R,Ko C H.Block-copolymer-templated ordered mesoporous silica:array of uniform mesopores or mesopore-micropore network[J].J.Phys.Chem.B,2000,104:11465-11471.
  • 8Jun S,Joo S H,Ryoo R,et al.Synthesis of new,nanoporous carbon with hexagonally ordered mesostructure[J].J.Am.Chem.Soc.,2000,122(43):10712-10713.
  • 9Fan Z L,Chen W,Pan X L,et al.Catalytic conversion of syngas into C2 oxygenates over Rh-based catalysts-effect of carbon supports[J].Catal.Today,2009,147:86-93.
  • 10Kong L B,Li H,Zhang J,et al.Platinum catalyst on ordered mesoporous carbon with controlled morphology for methanol electrochemicaloxidation[J].Appl.Surf.Sci.,2010,256:6688-6693.

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  • 1TAO CongLiang,LI JinLin,LIEW Kong Yong.Effect of the pore size of Co/SBA-15 isomorphically substituted with zirconium on its catalytic performance in Fischer-Tropsch synthesis[J].Science China Chemistry,2010,53(12):2551-2559.
  • 2毛肖,张九渊,薛进,董绍平,谢水海.换热器耐高温涂料的电化学阻抗谱特性分析[J].科技通报,2005,21(1):19-22. 被引量:5
  • 3BeckJ S, VartuliJ C, RothWJ, et al. A new family of mesoporous molecular sieves prepared with liquid crystal templats[J]. Journal of the American Chemical Society, 1992, 114(27): 10834-10843.
  • 4Kresge C T, Leonowicz M E, Roth W J, et al. Orderd me- soporous molecular sieves synthesized by a liquid-crystal template mechanism[J]. Nature, 1992, 359(6397):710- 712.
  • 5Niu Y F, Wang H, Zhu X L, et al. Ru supported on zirco- nia-modified SBA-15 for selective conversion of cellobiose to hexitols [J].Microporous and Mesoporous Materials, 2014, 198: 215-222.
  • 6Zhao D Y, Feng J L, Huo Q S, et al. Tribloek copolymer syntheses of mesoporous silica with periodic 50 to 300 ang- strom pores[J]. Science,1998, 279(5350) : 548-552.
  • 7Casagrande M, Storaro L, Lenarda M, et al. Highly se- lective Friedel-Crafts aeylation of 2- methoxy naphthlene catalyzed by H-Bea zeolite[J]. Applied Catalysis A.. Gen- eral, 2000, 201(2): 263-270.
  • 8Das D, Cheng S. Friedel-Crafts acylation of 2-methoxy naphthalene over zeolite catalysts [J]. Applied Catalysis A.. General, 2000, 201(2): 159-168.
  • 9Fromentin E, Coustard J M, Guisnet M. Acetylation of 2- methoxy naphthalene with acetic anhydride over a HBEA zeolite [J]. Journal of Molecular Catalysis A: Chemical, 2000, 159(2): 377-388.
  • 10Botella P, Corma A, Navarro M T, et al. On the shape selective acylation of 2-methoxy naphthalene over poly- morph of Beta (ITQ-17) [J]. Journal of Catalysis, 2003, 217(2) : 406-416.

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