摘要
The microstructure evolutions of two A1-Zn-Mg alloys, one of which was alloyed with Sc and Zr, and the kinetics of A13（SCl-xZrx） precipitates in the A1-Zn-Mg alloy during homogenization were investigated. Both alloys under as-cast condition with supersaturated, non-equilibrium T（Mg32（A1, Zn）49） phase and impurities phase were displayed. When the homogenization temperatures are below 350 ~C, Zn and Mg atoms precipitate from matrix; however, when the temperatures are above 400 ~C, T phase dissolves into matrix, enhancing solid-solution strengthening. Kinetics of A13（Scl.xZrx） precipitates was studied based on Jmat Pro software calculation and the difference values between the hardness of the two alloys in each homogenization condition. The calculations predict that the Sc and Zr solubilities in ct-A1 decline with the presence of Mg and Zn. Investigation of the difference values reveals that when the temperature is between 300 ~C and 350 ~C, the nucleation rate of A13（Sc1-xZrx） precipitates is the highest and the strengthening effect from A13（SCl_xZrx） precipitates is the best. After homogenization at 470℃ for 12 h, non-equilibrium T phase disappears, while impurity phase remains. The mean diameter of A13（Scl_xZrx） precipitates is around 18 urn. Ideas about better fulfilling the potentials of Sc and Zr were proposed at last.
The microstructure evolutions of two Al-Zn-Mg alloys,one of which was alloyed with Sc and Zr,and the kinetics of Al3(Sc1-xZrx) precipitates in the Al-Zn-Mg alloy during homogenization were investigated.Both alloys under as-cast condition with supersaturated,non-equilibrium T(Mg 32(Al,Zn) 49) phase and impurities phase were displayed.When the homogenization temperatures are below 350 C,Zn and Mg atoms precipitate from matrix;however,when the temperatures are above 400 C,T phase dissolves into matrix,enhancing solid-solution strengthening.Kinetics of Al3(Sc1-x Zr x) precipitates was studied based on Jmat Pro software calculation and the difference values between the hardness of the two alloys in each homogenization condition.The calculations predict that the Sc and Zr solubilities in α-Al decline with the presence of Mg and Zn.Investigation of the difference values reveals that when the temperature is between 300 C and 350 C,the nucleation rate of Al3(Sc1-xZrx) precipitates is the highest and the strengthening effect from Al3(Sc1-xZrx) precipitates is the best.After homogenization at 470 C for 12 h,non-equilibrium T phase disappears,while impurity phase remains.The mean diameter of Al3(Sc1-xZrx) precipitates is around 18 nm.Ideas about better fulfilling the potentials of Sc and Zr were proposed at last.
基金
Project(JPPT-115-2-948) supported by the National Civilian Matched Project of China
