摘要
对国内外电化学硼氢化的研究进行了综述。以电化学还原偏硼酸钠制备硼氢化钠为主线探讨了电极材料、电解液组成、电解槽和隔膜及添加剂等因素对电化学硼氢化的影响。论述了研究电化学还原偏硼酸钠的机理和重现性,并对其更进一步研究进行了展望。
In present paper, electrochemical hydroboration were reviewed, sodium borohydride synthesis with sodium metaborate through electrolysis were focused, and the effeets of electrode materials, electro- lyte, electrolytic cell, membrane and additives on the electrolysis were checked detailedly. Reproducibili- ty and the mechanism for sodium metaborate electrochemical reduction are summarizes, some directions for further study were given.
出处
《盐湖研究》
CSCD
2012年第4期57-62,72,共7页
Journal of Salt Lake Research
基金
中国科学院知识创新工程重要方向项目(KZCX2-EW-307)
关键词
硼氢化钠
燃料电池
电解
综述
Hydroboration
Fuel cells
Electrolysis
Review
