摘要
Mesoporous activated carbons were prepared from direct coal liquefaction residue （CLR） by KOH activation method, and the experiments were carried out to investigate the effects of KOH/CLR ratio, solvent for mixing the CLR and KOH, and carbonization procedure on the resultant carbon texture and catalytic activity for catalytic methane decomposition （CMD）. The results showed that optimal KOH/CLR ratio of 2 ： 1; solvent with higher solubility to KOH or the CLR, and an appropriate carbonization procedure are conductive to improving the carbon pore structure and catalytic activity for CMD. The resultant mesoporous carbons show higher and more stable activity than microporous carbons. Additionally, the relationship between the carbon textural properties and the catalytic activity for CMD was also discussed.
Mesoporous activated carbons were prepared from direct coal liquefaction residue （CLR） by KOH activation method, and the experiments were carried out to investigate the effects of KOH/CLR ratio, solvent for mixing the CLR and KOH, and carbonization procedure on the resultant carbon texture and catalytic activity for catalytic methane decomposition （CMD）. The results showed that optimal KOH/CLR ratio of 2 ： 1; solvent with higher solubility to KOH or the CLR, and an appropriate carbonization procedure are conductive to improving the carbon pore structure and catalytic activity for CMD. The resultant mesoporous carbons show higher and more stable activity than microporous carbons. Additionally, the relationship between the carbon textural properties and the catalytic activity for CMD was also discussed.
基金
supported by the National Natural Science Foundation of China(No.20906009)
the Key Program Project of Joint Fund of Coal Research by NSFC and Shenhua Group(No.51134014)
the Fundamental Research Funds for the Central Universities(No.DUT12JN05)
the National Basic Research Program of China(973Program)
the Ministry of Science and Technology,China(No.2011CB201301)
