摘要
在铁试剂(7-碘-羟基喹啉-5-磺酸,即Ferron)、溴化十六烷基吡啶(CPB)存在下,于pH4.3的乙酸-乙酸铵介质中,铝、铁分别生成Al-Ferron-CPB、Fe-Ferron-CPB三元络合物,采用双波长分光光度法,选测量波长390.0nm,参比波长445.1nm波长组合测定铝,单波长630mn测定铁,用此方法测定硅铁中的铁和铝,结果比较满意。
A method of dual-wavelength spectrophotomentry is applied to determination of Al and Fe inferrosilion. The measuring wavelength and referential wavelength are 390. 0 nm and 445. 1 nm for Al630. 0 nm for Fe. The respective relative deviation is 0. 011 and 0. 023, the coeffcient is 1. 30% and 0. 40%for Al and Fe. The method is repid, simple with satisfactory results.
出处
《齐齐哈尔大学学报(自然科学版)》
2000年第1期92-94,共3页
Journal of Qiqihar University(Natural Science Edition)
关键词
双波长分光光度法
铁
铝
CPB
铁试剂
硅铁
dual wave-length spectrophotomtry
aluminiumiron
ferrosilicon
ferron
CPB
ternary micellar complex