摘要
To develop new type of high damping metal matrix composites, large grain size barium titanate （BaTiO3） ceramic was sintered and added into Al powder to fabricate BaTiO3/Al composites through the powder metallurgy method and hot extrusion. The damping properties of BaTiO3 ceramic, Al matrix and BaTiO3/Al composites were examined by dynamic mechanical analysis in the temperature range from 273 K to 573 K. The results show that although BaTiO3 exhibits high damping （tan δ=0.12） below 400 K, the damping capacity of 10%BaTiO3/Al （mass fraction） composites below 400 K is not increased as compared to the Al matrix. On the other hand, the damping capacity above 450 K is greatly enhanced due to the motion of dislocations at the interfaces between ceramic particles and Al matrix. The failure of exerting the intrinsic damping of BaTiO3 particles in the composites is attributed to the poor interface bonding between the particles and the matrix. The tensile strength of the composite is 42% higher than that of the Al matrix, which indicates the possibility of obtaining high strength and high damping composites via interface improvement and the addition of high volume fraction of large grain BaTiO3 particles.
为了开发新型高阻尼金属基复合材料,以高温烧结后的大晶粒钛酸钡(BaTiO3)陶瓷作为增强体,通过粉末冶金和热挤压方法制备钛酸钡颗粒增强铝基复合材料,并研究其阻尼特性和力学特性。动态力学分析结果表明,大晶粒钛酸钡陶瓷本身具有很好的阻尼性能,阻尼值可达0.12。但在纯铝基体中加入质量分数为10%BaTiO3制备的BaTiO3/Al复合材料的室温阻尼性能和铝基体相比并无明显改善,而450K以上的阻尼性能由于界面附近的位错运动而大幅度提高。钛酸钡增强体的本征阻尼性能未能充分发挥的原因在于钛酸钡颗粒与铝基体之间的界面结合不良,导致钛酸钡颗粒内部的能量耗散机制无法触动。复合材料的拉伸性能比相应纯铝基体的提高了42%,这意味通过改善界面结合和加入高含量的碳酸钡阻尼增强颗粒,有望获得高强度高阻尼金属基复合材料。
基金
Project (51001071) supported by the National Natural Science Foundation of China
Projects (2012CB619400, 2012CB619600) supported by the National Basic Research Program of China
Project (2010DFA52550) supported by the International S&T Cooperation Program of China
Project (20100470031) supported by China Postdoctoral Science Foundation
