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硼砂交联低聚羟丙基塔拉胶可再生凝胶体系的制备与流变性研究 被引量:8

The Preparation and Rheological Properties of Regeneratable Borax/Degrated Hydroxypropyl Tara Gum Gel Systems
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摘要 开发低成本可再生压裂液对油气田强化开采具有重要意义。今合成了低聚羟丙基塔拉胶,表征了双氧水对其降解程度的影响,考察了低聚羟丙基塔拉胶浓度和硼砂浓度对凝胶形成的影响,得到了稳定的硼砂交联可再生凝胶体系。考察了不同再生次数凝胶体系的流变性,结果表明再生3次以下的凝胶体系具有良好的黏弹性、触变性和剪切变稀性,再生前后凝胶体系流变性无显著变化。该可再生凝胶体系的流变曲线可用非线性共转Jeffreys模型描述,实验值与模拟值吻合良好。 It is important to develop regeneratable fracturing fluid with low cost for enhanced exploitation of oil-gas fields.In this paper,the Degrated Hydroxypropyl Tara Gum(DHPTG) was synthesized,and the influence of hydrogen peroxide dosage on its degradation degree was studied.The effects of DHPTG and borax concentrations on the formation of gel systems were investigated,and stable borax cross-linked DHPTG regeneratable gel systems were obtained.Furthermore,the rheological properties of the gel systems with different regeneration times were investigated.The results show that the gel systems with less than 3 regeneration times possess good visco-elasticity,thixotropy,and shear thinning properties,and the rheological properties of the gels before and after regeneration are not changed significantly.It was found that the non-linear co-rotational Jefferys model can be used to describe the flow curves of regeneratable gel systems correctly,and the calculated values are in good agreement with the experimental data.
作者 朱广宇 方波
出处 《高校化学工程学报》 EI CAS CSCD 北大核心 2012年第5期901-904,共4页 Journal of Chemical Engineering of Chinese Universities
关键词 低聚羟丙基塔拉胶 硼砂交联 可再生 黏弹性 触变性 剪切变稀性 degrated hydroxypropyl tara gum borax cross-linked regeneratable visco-elasticity thixotropy shear thinning property
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  • 1刘静,管保山,周晓群,吕海燕,李转红,张喜凤,郭自新.新型低分子压裂液流变性研究[J].油气井测试,2008,17(5):4-6. 被引量:7
  • 2Peles J,Wardlow R W.Maximizing well production with unique low molecular weight fracturing fluid[C] //SPE 77746.International Symposium on Oilfield Chemistry,Houston:Society of Petroleum Engineers Inc,2002.
  • 3高成武,尹淑丽,赵光勇,李彦林.低聚合物压裂液的研究及应用[J].新疆石油科技,2003,13(2):13-17. 被引量:7
  • 4管保山,汪义发,何治武,杜彪,刘静.CJ2-3型可回收低分子量瓜尔胶压裂液的开发[J].油田化学,2006,23(1):27-31. 被引量:49
  • 5Yu C,Kirk M B,Robert K P.Preparation and characterization of molecular weight fractions of guar galactomannans using acid andenzymatic hydrolysis[J].International Journal of Biological Macromolecules,2002,31(1):29-35.
  • 6Parker M,Slabaugh B,Walters H,et al.New hydraulic fracturing fluid technology reduces impact on the environment throughrecovery and reuse[C] //SPE 80590,International Symposium on Oilfield Chemistry.Houston:Society of Petroleum EngineersInc,2003.
  • 7刘东,孔学,李美玉,王宗贤,阙国和.噻吩在硫化态Mo基催化剂表面的吸附行为[J].石油学报(石油加工),2008,24(6):657-662. 被引量:8
  • 8Tetsuya M,Toshitaka F.Noncatalytic hydrolysis of guar gum under hydrothermal conditions[J].Carbohydrate Research,2006,341(7):870-877.
  • 9Shobhaa M S,Vishu Kumar A B,Tharanathan R N,et al.Modification of guar galactomannan with the aid of aspergillus nigerpectinase[J].Carbohydrate Polymers,2005,62(3):267-273.
  • 10Naoi S,Hatakeyama T,Hatakeyama H.Phase transition of locust bean gum,tara gum and guar gum water systems[J].Journal ofThermal Analysis and Calorimetry,2002,70(3):841-852.

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