摘要
Selective hydrogenation of α, β-unsaturated aldehydes with modified Pd/C catalyst was developed.The reduction of C=O bond could be efficiently inhibited by the addition of carbonates,and high selectivity to the corresponding saturated aldehydes was achieved under mild conditions.This protocol provides an alternative for efficient preparation of saturated aldehydes.
Selective hydrogenation of α, β-unsaturated aldehydes with modified Pd/C catalyst was developed.The reduction of C=O bond could be efficiently inhibited by the addition of carbonates,and high selectivity to the corresponding saturated aldehydes was achieved under mild conditions.This protocol provides an alternative for efficient preparation of saturated aldehydes.
基金
supported by the National High Technology Research and Development Program of China(863 Project)(No.2007AA03Z345)
the Scientific Research Project for Institute of Higher Education of Education Bureau,Liaoning(No.LT2010021)
the Fundamental Research Funds for Dalian University of Technology(No.DUT10RC(3)107)
