摘要
NaBH4还原体系可以快速、高效、选择性地还原羧酸及其衍生物。本文介绍了8类NaBH4还原体系的最近研究成果。通过对各个还原体系的分析,讨论了各类还原体系的反应机理和反应条件,并比较了不同还原体系的还原能力和适用范围。
The sodium borohydride system is a group of chemical reagents with rapid, effective and selective specificities in the reduction of earboxylic acid and its derivatives. In this paper, eight categories of sodium borohydride reduction system were introduced. The recent progress in the reaction mechanism and conditions, as well as the reduction capacity and application scope of the reduction system were reviewed.
出处
《化学通报》
CAS
CSCD
北大核心
2012年第7期614-620,共7页
Chemistry
基金
国家重点基础研究发展计划(2007CB512102)资助
关键词
硼氢化钠
还原反应
羧酸
羧酸衍生物
Sodium borohydride, Reduction, Carboxylic acid, Carboxylic acid derivatives