摘要
采用5%次氯酸钠水溶液为氧化剂,Tempo为催化剂,由3-羟基环庚酮缩乙二醇制备1,3-环庚酮,收率高,成本低,无三废,可扩大生产。
Hydroxycycloheptanone ethylene ketal was nearly quantitatively oxidized to the corresponding ketone by5 % sodium hypochlorite solution mediated by oxoammonium salt( Tempo) ,to offer a safe,low cost and waste free manufacture method.
出处
《中国医药工业杂志》
CAS
CSCD
北大核心
2000年第1期37-38,共2页
Chinese Journal of Pharmaceuticals
关键词
醛
酮
次氯酸钠
氧化法
TEMPO
alcohol
oxidation
aldehyde
ketone
oxoammonium salt( Tempo)
sodium hypochlorit
