摘要
以薄荷醇和8-甲氧基香豆素-3-甲酸为原料,合成了一种新型、释放型清凉剂8-甲氧基香豆素-3-甲酸薄荷酯,产物的结构经IR、1H NMR、13C NMR和HRMS确证.采用在线裂解气相色谱-质谱联用技术,对8-甲氧基香豆素-3-甲酸薄荷酯在600℃下的裂解行为进行了研究,并对8-甲氧基香豆素-3-甲酸薄荷酯进行了卷烟加香试验.结果表明:(1)600℃时,香豆素-3-甲酸薄荷酯的热解产物中共鉴定出25种成分,其中多种为重要的烟草香味成分;(2)8-甲氧基香豆素-3-甲酸薄荷酯具有改善和修饰卷烟烟气,增加豆香与清凉香气,减轻刺激性的作用.
8-methoxycoumarin-3-carboxylic acid menthyl ester was synthesized from menthol and 8-me- thoxycoumarin-3-carboxylic acid, and its structure was characterized by IR, 1H NMR, 13C NMR and HRMS. Pyrolysis products of the title compound was studied by means of pyrolysis-GC/MS at 600℃ , and the effect of the title compound on flavor of cigarettes by smoking was preliminarily evaluated. The results show that： 1 ） 25 compounds were identified at 600℃ , and most of them were important aroma components of tobacco ; 2） 8-methoxycoumarin-3-carboxylie acid menthyl ester can improve the flavor, enhance the notes of bean aroma and cool refreshing, as well as reduce the harshness of cigarette smoke.
出处
《河南农业大学学报》
CAS
CSCD
北大核心
2012年第1期26-30,共5页
Journal of Henan Agricultural University
基金
河南省教育厅基金项目(2009A150012)
