摘要
Four alkoxo complexes [Cp 2Mo(PMe 3)OR] +OTs -(R=Me, Et, Pr n , Pr i ) were synthesized and characterized by IR, 1H NMR and elemental analysis. The β hydrogen elimination of these complexes in dimethyl sulfoxide gave monohydrido complex [Cp 2Mo(PMe 3)H] +OTs - and a ketone or aldehyde.
Four alkoxo complexes [Cp 2Mo(PMe 3)OR] +OTs -(R=Me, Et, Pr n , Pr i ) were synthesized and characterized by IR, 1H NMR and elemental analysis. The β hydrogen elimination of these complexes in dimethyl sulfoxide gave monohydrido complex [Cp 2Mo(PMe 3)H] +OTs - and a ketone or aldehyde.
出处
《应用化学》
CAS
CSCD
北大核心
2000年第1期81-83,共3页
Chinese Journal of Applied Chemistry
基金
国家自然科学基金! ( 2 9872 0 2 4 )
山西省归国留学人员基金
关键词
钼烷氧基配合物
合成
β-H消去反应
alkoxo complex molybdenum,synthesis, β hydrogen elemination
