期刊文献+

碳纳米管/聚乳酸复合材料的制备与性能 被引量:5

Preparation and Properties of Carbon Nanotubes/Poly(Lactic Acid) Composites
在线阅读 下载PDF
导出
摘要 用熔融共混的方法制备了碳纳米管(CNTs)/聚乳酸(PLA)复合材料,观察了其球晶形貌和断面形貌,并研究了不同配比的CNTs/PLA复合材料的结晶性能和水解性能。结果表明:CNTs可以作为异相成核剂提高PLA的结晶速率和结晶度,CNTs质量分数为1%时,复合材料的结晶度达到44.9%,CNTs能够在基体中均匀分散;CNTs质量分数小于1%时,断面呈中间层破形貌;随CNTs含量增多,复合材料的球晶直径变大;CNTs能降低PLA的水解速率。 Carbon nanotubes(CNTs)/poly(lactic acid)(PLA) composites were prepared by melt blending method.The morphology of spherulitic crystal and fracture was observed,and the crystallinity and the hydrolysis properties of CNTs/PLA composites with different ratios were studied.The results show that CNTs could act as heterogeneous nucleators and increase the crystallinity rate and degree of PLA,the crystallinity degree could reach 44.90% when CNTs content was 1wt%,and CNTs could disperse homogenously in matrix.The fracture took on mid-layer damage morphology when CNTs content was less than 1wt%,and the spherulitic crystal diameter of composite increased with the increase of CNTs content,CNTs could reduce the hydrolysis rate of PLA.
出处 《机械工程材料》 CAS CSCD 北大核心 2012年第1期37-40,共4页 Materials For Mechanical Engineering
关键词 聚乳酸 碳纳米管 复合材料 性能 poly(lactic acid)(PLA) carbon nanotube(CNT) composite property
  • 相关文献

参考文献5

  • 1CURRAN S A,ZHANG Dong-hui,SEAMUS A,et al.Dy-namic electrical properties of polymer-carbon nanotube com-posites:enhancement through covalent bonding[J].Journal of Materials Research,2006,4(21):1071-1077.
  • 2SONG W H,ZHENG Z,TANG W L,et al.A facile ap-proach to covalently functionalized carbon nanotubes with bio-compatible polymer[J].Polymer,2007,48:3658-3663.
  • 3WU C S,LIAO H T.Study on the preparation and character-ization of biodegradable polylactide/multi-walled carbon nano-tubes nanocomposites[J].Polymer,2007,48:4449-4458.
  • 4张艺,程开良,许家瑞.调制式差示扫描量热法在高分子研究中的应用[J].化学通报,2004,67(5):341-348. 被引量:12
  • 5PLUTA M,PAUL MA,AlEXANDRE,et al.Plasticized polylactide/clay nano composites,Part II:The effect of aging on structure and properties in relation to the filler content and the nature of its organ modification[J].J Polym Sci B Polym Phys,2006,44 (2):312-315.

二级参考文献30

  • 1朱支蔷,张弓.用调制式DSC测量高聚物的结晶度[J].化学世界,2000,41(S1). 被引量:2
  • 2王国男,林金土.用MDSC测量高聚物的结晶度[J].化学世界,1995,36(9):480-482. 被引量:2
  • 3M Reading,D Elliol,V L Hill.Proc.9th ICTA Meeting,Hatfileld,UK,August 1992;J.Thern.Anal.,1993,40:949-955.
  • 4M Reading.Trends Polym.Sci.,1993,8(1):248-253.
  • 5M Reading.USP:5224775,5248199,1993.
  • 6E Y Ding,R S Cheng.Thermochim.Acta,2001,378:51-68.
  • 7D H Krzystowczyk.Polym.Bull.,1994,33:109-112.
  • 8Z Jiang,JMHutchinson,C T Imrie.Polym.Int.,1998,47(1):72-75.
  • 9C C Torregrosa.J.Non-Crystal.Solids,2002,307-310:731-737.
  • 10J M Vickery.Thermalchim.Acta,2001,367-368:177-184.

共引文献11

同被引文献36

引证文献5

二级引证文献13

相关作者

内容加载中请稍等...

相关机构

内容加载中请稍等...

相关主题

内容加载中请稍等...

浏览历史

内容加载中请稍等...
;
使用帮助 返回顶部