摘要
用模板合成的方法,由2,6—二乙酰吡啶和间苯二胺在铀酰离子的模板作用下,首次缩合制成硝酸铀酰的二十元六氮大环配合物UO_2(NO_3)_2(C_(30)H_(26)N_6)·2H_2O.,并对配合物的化学组成,光谱及摩尔电导等性质进行了讨论。
A novel coordination compound of hexadentate nitrogen donor macrocycle.UO_2 (NO_3)_2·(C_(30)H_(26)N_6)·2H_2O has been obtained by the template condensation of 2,6—diacetyl pyridine with meta—phenylene diamine in the presence of uranyl nitrate. Its properties of spectra, thermal stability and molar conductance etc. have been studied.
出处
《郑州大学学报（自然科学版）》
CAS
1990年第1期65-67,共3页
Journal of Zhengzhou University (Natural Science)
关键词
硝酸铀酰
配合物
二乙酰吡啶
Uranyl nitrate, 2, 6—diacetyl pyridine, coordination compound.
