摘要
巯基参与的点击反应具有简单、快速、无金属催化等优点。本文介绍了巯基点击反应的反应机理,着重对近年来新出现的巯基点击反应的概念、特点进行分类介绍,并综述了巯基点击反应在材料与分子设计方面的应用,最后对其发展前景进行了展望。
Thiol-based click reaction had prominent advantages such as convenience, quickness, metal-free catalysis. Firstly, the reaction mechanism of thiol-based click reaction was introduced. Then, the conception and characteristics of some newly developed thiol-based click reactions in recent years were reviewed in details, followed by the potential applications of the reaction in molecular design and functional materials. Finally, some drawbacks and prospects of the reaction were also summarized.
作者
付长清
程传杰
申亮
陈义旺
FU Chang-qing;CHENG Chuan-jie;SHEN Liang;CHEN Yi-wang(Institute of Polymers,Nanchang University,Nanchang 330031,China;Research Institute of Organic Functional Molecule,Jiangxi Science&Technology Normal University,Nanchang 330013,China)
出处
《高分子通报》
CAS
CSCD
北大核心
2012年第1期29-36,共8页
Polymer Bulletin
基金
国家自然科学基金项目(51063002)
江西省教育厅青年科学基金项目(GJJ09575)
江西科技师范学院校科研项目(KY2010ZY05)
关键词
巯基点击反应
点击化学
分子设计
应用
Thiol-based click reaction
Click chemistry
Molecular design
Application
