摘要
简要介绍了有机电化学合成体系的研究方法和技术关键及主要特征.以CC类化合物为例阐明了有机电化学合成中的各类反应,己二腈电合成的工业化应用,并例举CO2的电化学固定利用,展现现今有机电化学合成的研究动向.
Organic electrochemistry is a very useful tool for organic synthesis,not only because of the selective introduction or removal of electrons from organic molecules,but also for its green process.In this paper,electroorganic synthesis has been introduced from the systems,research methods and technologies to the characterization.Most of organic compounds could be electrochemically oxidized or reduced.Here,taking C C compounds as an example,several kinds of electrochemical organic synthesis reactions are discussed,such as electrochemical addition,electrocatalytic dimrization,electropolymerization,etc.Electroorganic synthesis has been industrialized since 1960s.In this paper,electrosynthesis of adiponitrile was used as an example to introduce the manufacturing technique and technological improvement.Electrochemical fixation of CO2 is also introduced.At last,future outlook is also described.
出处
《电化学》
CAS
CSCD
北大核心
2011年第4期366-372,共7页
Journal of Electrochemistry
基金
国家自然科学基金(20973066,21173085)资助
关键词
有机电化学
电化学合成
绿色化学
organic electrochemistry
electrosynthesis
green chemistry
