摘要
采用原位聚合法制备了聚酰胺11/石墨烯氧化物(PA11/GO)纳米复合材料,利用差示扫描量热仪研究了PA11和PA11/GO纳米复合材料的非等温结晶过程和熔融行为,并通过Jeziorny法和Mo法研究了PA11及其复合材料的非等温结晶动力学。结果表明,PA11和PA11/GO纳米复合材料均呈现双重熔融峰。GO的加入抑制了PA11的结晶行为,降低了结晶速率。GO会影响PA11的成核和晶体生长规律。
Polyamide 11/graphene oxide （PA11/GO） nanocomposites were prepared via in-situ polymeri- zation. Non-isothermal crystallization and melting behaviors of PAll and PA11/GO nanocomposites were investigated using differential scanning calorimetry, and Non-isothermal crystallization kinetics of them was analyzed by Jeziorny and Mo method. It was found that both PAll and PA11/GO nanocomposites displayed double melting peaks. The addition of GO decreased the crystallization rate of PA11. The mechanisms of nucleation and growth of crystallization were changed by adding GO.
出处
《中国塑料》
CAS
CSCD
北大核心
2011年第10期44-49,共6页
China Plastics
关键词
聚酰胺11
石墨烯氧化物
原位聚合
非等温结晶动力学
熔融行为
polyamide 11
graphene oxide
in-situ polymerization
non-isothermal crystallizationkinetics
melting behavior
