期刊文献+

CuCr_2O_4/TiO_2复合薄膜电极对染料敏化太阳能电池光电性能的影响 被引量:3

Effect of CuCr_2O_4/TiO_2 composite film electrodes on DSSC photoelectric properties
在线阅读 下载PDF
导出
摘要 将制备的CuCr2O4纳米粉体以不同比例掺杂到TiO2粉体中制成浆料,采用丝网印刷法在FTO导电玻璃上制备CuCr2O4/TiO2复合薄膜电极。利用X射线衍射仪对复合薄膜进行晶型分析,数显测厚指示表测试复合薄膜的厚度,用光电转换测定仪测试了DSSC性能。结果表明,掺杂CuCr2O4纳米粉体能够提高电池的光电转化效率,当薄膜厚度为20μm、掺杂粉体的质量分数为2%时,薄膜电极具有良好的光电性能;与纯TiO2薄膜电极相比,光电转化效率提高了22.6%,达到6.5%。 CuCr204/TiO2 composite film electrodes were prepared on FTO glass substrate by screen printing method after CuCr2O4 nanoparticles were doped in TiO2 powder. The characteristics were studied by the X ray diffraction for the crystalline structure of composite film, digital thickness instruction for the thickness of composite film and dye sensitized solar cells tester for the performance of DSSC. The results showed that doping CuCr2O4 nano-powders could improve the photoelectric conversion efficiency of the solar cells when the thickness of film was 20 μm and the content of CuCr,04 was 2%. Compared with pure TiO2 film electrode, the photoelectric conversion efficiency of the solar cells was increased by 22.6 % and reached to 6.5 %.
出处 《大连工业大学学报》 CAS 北大核心 2011年第5期357-360,共4页 Journal of Dalian Polytechnic University
基金 国家高技术研究发展计划(863计划)项目(2006AA05Z417) 辽宁省教育厅重点实验室科技项目(2008S017)
关键词 染料敏化太阳能电池(DSSC) 复合薄膜 光电性能 dye-sensitized solar cells(DSSC) composite film photoelectric property
  • 相关文献

参考文献9

  • 1O'REGAN B, GRATZEL M. A low-cost, high ef- ficiency solar cell based on dye-sensitized colloidal TiO2 films[J]. Nature, 1991, 353:737 -740.
  • 2NAZEERUDDIN M K, KAY A, RODICIO R, et al. Conversion of light to electricity by cis-X bis (2,2'- bipyridyl-4,4'- dicarboxyiate) ruthenium ( II) charge- transfer sensitizers (X=Cl^- , Br^- , I^- , CN^- , and SCN ) on nanoerystalline TiO2 electrodes[J]. Jour nal of the American Chemical Society, 1993, 115 (14) : 6382-6390.
  • 3BACH U, LUPO D, COMTE P, et at. Solid state dye-sensitized mesoporous TiO2 solar cells with high photo-to electron conversion efficiencies[J]. Nature, 1998, 395:583-585.
  • 4GRATZEL M. Photoelectrochemical cells[J]. Na -ture, 2001, 414:338-344.
  • 5KOK H, I.EEYC, JUNG YJ. Enhanced efficiency of dye-sensitized TiO2 solar cells (DSSC) by doping of metal ions[J]. Journal of Colloid and Interface Sci ence, 2005, 283(2) :482-487.
  • 6KITIYANAN A, YOSHIKAWA S. The use of ZrO2 mixed TiO2 nanostructures as efficient dye-sensitized solar cells electrodes[J]. Materials Letters, 2005, 59 ( 29/30) : 4038-4040.
  • 7YAN Jianhui, ZHANG Li, YANG Haihua, et al. CuCr2O4/TiO2 heterojunction for photocatalytic H2 e- volution under simulated sunlight irradiation[J]. Solar Energy, 2009, 83(9):1534-1539.
  • 8高岩,胡志强,李国,高文元,姜妍彦.低温制备柔性染料敏化太阳电池TiO_2薄膜电极[J].电子元件与材料,2007,26(7):4-6. 被引量:10
  • 9姜妍彦,李景刚,宁桂玲,王承遇.尖晶石型CuAl_2O_4纳米粉体的制备及其可见光催化性能[J].硅酸盐学报,2006,34(9):1084-1087. 被引量:26

二级参考文献17

  • 1李新勇,李树本,吕功煊.纳米尺寸铁酸锌半导体催化剂的表征及催化性能研究[J].分子催化,1996,10(3):187-193. 被引量:34
  • 2FUJISHIMA A,HONDA K.Electrochemical photolysis of water at a semiconductor electrode[J].Nature,1972,238:37-38.
  • 3YIN J,ZOU Z G,OSHIKILI M,et al.A novel series of visible light driven ABO3 perovskite photocatalysts with special 3D electronic configuration[A].In:Li C.The 3rd Asia-Pacific Congress on Catalysis[C].Dalian:Dalian Institute of Chemical Physics Press,2003.584.
  • 4JINHUA Y,ZHIGANG Z,OSHIKIRI M.et al.A novel hydrogen-evolving photocatalyst InVO4 active under visible light irradiation[J].Chem Phys Lett,2002,356:221-226.
  • 5JUAN M C,MA.T L,MAMUEL S,et al.Solar photocatalystic degradation of azodyes by photo-Fenton process[J].Dyes Pigments,2005,69:144-150.
  • 6BESSEKHOUND Y,TRARI M.Photocatalystic hydrogen production from suspension of spinel powders AMn2O4 (A=Cu and Zn)[J].Int J Hydrogen Energy,2001,27:357-362.
  • 7WANG Defa,ZOU Zhigang.A new spinel-type photocatalysts BaCr2O4 for H2 evolution under UV and visible light irradiation[J].Chem Phys Lett,2003,373:191-196.
  • 8GUO Yihang,LI Danfeng,HU Changwen.Preparation and photocatalystic behavior of Zn/Al/W(Mn) mixed oxides via polyoxometalates intercalated layered double hydroxides[J].Microporous Mesoporous Mater,2002,56:153-162.
  • 9AYANA Tomita,TOKUSHI Sato.Luminescence channels of manganese-doped spinel[J].J Lumin,2004,109:19-24
  • 10B EATA Z,MORAWSKI A W.TiO2 photocatalysts promoted by alkali metals[J].Appl Catal B:Environ,2005,55:221-226.

共引文献34

同被引文献35

引证文献3

二级引证文献12

相关作者

内容加载中请稍等...

相关机构

内容加载中请稍等...

相关主题

内容加载中请稍等...

浏览历史

内容加载中请稍等...
;
使用帮助 返回顶部