期刊文献+

利用FT-IR研究硫酸盐侵蚀后混凝土表层的胀裂(英文) 被引量:5

The Spalling and Pulverization of Concrete Surface Under Sulfate Attack:An Investigation by FT-IR
在线阅读 下载PDF
导出
摘要 为了研究由硫酸盐侵蚀而导致的混凝土里表不同部位侵蚀的变化特征,利用傅里叶变换红外光谱定性地研究了在10%硫酸钠溶液中浸泡4年的混凝土试件内部的侵蚀产物分布规律。研究表明:在该类侵蚀介质的作用下,混凝土内主要侵蚀产物为石膏和钙矾石;在界面过渡区和水泥石基体中,石膏的含量沿着混凝土厚度方向减少,钙矾石增加;在同一厚度下,界面过渡区中钙矾石和氢氧化钙的含量高于水泥石基体中钙矾石和氢氧化钙的含量。 This paper presented results from an investigation program that concrete was eroded by sodium sulfate solution by means of Fourier transform infrared spectrum (PF-IR). The results showed that the primary deterioration products of concrete suffered from sodium sulfate attack are gypsum and ettringite. In interfaeial transition zone (ITZ) , the quantity of gypsum decrease along thickness direction while the quantity of ettringite increase. In paste matrix, the quantity of gypsum is less and less while the quantity of ettringite is more and more from enterior to interior. The quantities of ettringite in ITZ are more than that in paste matrix.
出处 《硅酸盐通报》 CAS CSCD 北大核心 2011年第4期909-914,共6页 Bulletin of the Chinese Ceramic Society
基金 Support of National High Technology Research and Development Program 863(No.2007AA03Z526)
关键词 硫酸盐侵蚀 混凝土 界面过渡区 傅里叶变换红外光谱 sulfate attack concrete ITZ FT-IR
  • 相关文献

参考文献14

  • 1李长成,姚燕,王玲.内掺硫酸镁加速水泥基材料TSA破坏[J].硅酸盐学报,2010,38(7):1197-1200. 被引量:6
  • 2李贵强,芦令超,王守德,陈诚,尹超男.阿利特-硫铝酸钡钙水泥抗硫酸盐侵蚀性能的研究[J].硅酸盐通报,2009,28(5):1038-1041. 被引量:12
  • 3王复生,孙瑞莲,秦晓娟.察尔汗盐湖条件下水泥混凝土耐久性调查研究[J].硅酸盐通报,2002,21(4):16-22. 被引量:68
  • 4Sarkar S,Mahadevan S,Meeussen J C L,et al.Numerical simulation of cementitious materials degradation under external sulfate attack. Cement and Concrete Research . 2010
  • 5Zhang J X,Sun H H,Wan J H,et al.Study on microstructure and mechanical property of interfacial transition zone between limestone aggregateand sialite paste. Construction and Building Materials . 2009
  • 6Pipilikaki P,Papageorgiou D,Dimitroula M,et al.Microstructure changes in mortars attacked by sulphates at 5℃. Construction andBuilding Materials . 2009
  • 7Pajares I,Ramírez S M,Blanco-Varela M T.Evolution of ettringite in presence of carbonate,and silicate ions. Cement and ConcreteComposites . 2003
  • 8Anbalagan G,Mukundakumari S,Murugesan K S,et al.Infrared,optical absorption,and EPR spectroscopic studies on natural gypsum. Vibrational Spectroscopy . 2009
  • 9Trezza M A,Lavat A E.Analysis of the system 3CaO.Al2O3-CaSO4.2H2O-CaCO3-H2O by FT-IR spectroscopy. Cement and Concrete Research . 2001
  • 10Pajares I,Ramírez S M,Blanco-Varela M T.Evolution of ettringite in presence of carbonate,and silicate ions. Cement and ConcreteComposites . 2003

二级参考文献17

共引文献83

同被引文献43

  • 1Hartman M R, Bediner R. Investigation of the structure of ettringite by time-of-flight neutron powder diftaction techniques [ J ]. Cement and concrete research,2006,36 ( 2 ) : 364-370.
  • 2Havlica J, Sahu S. Mechanism of ettringite and monosulphate formation [ J ]. Cement and concrete research, 1992,22 (4) :671 677.
  • 3Min D, Mingshu T. Formation and expansion of ettringite crystals[ J ]. Cement and Cmwrete Research, 1994,24 (1) : 119-! 26.
  • 4Pollmann H, Kuzel H ], Wenda R. Compounds with ettringite structure [ I ]. Nettes Jahrbuch Ftr Mineralogie-Abhandhmgen, 1989,160 ( 2 ) : 133- 158.
  • 5Kapr(llik I, Hanic F. Phase relations in the subsystem CaA3S-C S H2-CH-H20 of the system CaO-A1203-CS-H20 retrred to hydration of sulphoaluminate cement [ J ]. Cement and Concrete Research, 1989,19 ( 1 ) : 89-102.
  • 6陈益民,许仲梓,高性能水泥制备和应用的科学基础[M].化学工业出版社,2008.
  • 7Clark B A, Brown P W. Formation of ettringite from monosubstituted calcium sulfoaluminate hydrate and gypsum [ J ]. Jourmd of the American Ceramic Society, 1999,82 ( 1 O) :2900 -2905.
  • 8Palou M T, Majling J. Hydration in the system C4 A3 S-C SH2 -CH-H [ J ]. Journal of thermal analysi.% 1996,46 ( 2 ) : 557-563.
  • 9钟白茜,杨南如.钙矾石的形成和稳定条件[J].硅酸盐学报.1984,12(2):11一14.
  • 10Mehta P K. Mechanism of expansion associated with ettringite formation [ J ]. Cement and Concrete Research, 1973,3 ( 1 ) : 1 1o.

引证文献5

二级引证文献49

相关作者

内容加载中请稍等...

相关机构

内容加载中请稍等...

相关主题

内容加载中请稍等...

浏览历史

内容加载中请稍等...
;
使用帮助 返回顶部