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温度对碳硫硅钙石形成的影响 被引量:26

EFFECTS OF TEMPERATURES ON THAUMASITE FORMATION
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摘要 研究了环境温度对碳硫硅钙石形成的影响.将浸泡于不同温度的质量分数为10%的MgSO4溶液中的含石灰石粉水泥石试样进行X射线衍射分析、扫描电子显微分析、能谱分析和激光Raman光谱分析.结果表明:掺石灰石粉的水泥石在0~10℃的温度范围内,可形成碳硫硅钙石的硫酸盐侵蚀破坏.环境温度越低,碳硫硅钙石形成得越早. Effects of temperatures on thaumasite formation were investigated. X-ray diffraction, scanning electron microscope, energy dispersive spectrum and laser Raman spectrum analysis were used to identify thaumasite in paste sample stored in 10% (in mass) of MgSO4 solution at different temperatures. Results show that paste containing ground limestone can be destroyed at the temperature of 0-10°C by the sulphate attack of thaumasite form. The lower the temperature is, the earlier the thaumasite formation is.
出处 《硅酸盐学报》 EI CAS CSCD 北大核心 2005年第4期525-527,共3页 Journal of The Chinese Ceramic Society
基金 "973"计划(2001CB6107)资助项目。
关键词 温度 碳硫硅钙石 温度 侵蚀机理 混凝土 石灰石 能谱分析法 Chemical attack Durability Energy dispersive spectroscopy Raman spectroscopy Scanning electron microscopy Temperature X ray diffraction analysis
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参考文献2

  • 1SAHU S, BADGER S, THAULOW N. Evidence of thaumasite formation in southern California concrete[J]. Cem Concr Compos, 2002, 24: 379-384.
  • 2SAHU S, EXLINE D L, NELSON M P. Identification of thaumasite in concrete by Raman chemical imaging[J]. Cem Concr Compos, 2002, 24: 347-350.

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