摘要
综述了近十年来绿色化学试剂过氧化氢在合成亚砜、砜、环氧化物、醇、酚、醛、酮、酸、酯、卤代物等各种有机化合物中的研究进展,也论述了一些新的合成反应介质体系,如离子液体、氟相、超临界流体等绿色介质与过氧化氢结合在有机合成中的应用,希望能促进绿色化学技术的研究与应用,促进化学的可持续发展.
The developments of organic synthesis using hydrogen peroxide as a green chemical reagent are reviewed in synthesizing various organic compounds, such as sulfoxides, sulfones, epoxy compounds, alcohols, phenols, aldehydes, ketones, carboxylic acids, esters and halides in recent ten years. The applications of hydrogen peroxide combining with some new classes of green reaction media including ionic liquids, fluorous phase solvents, and supercrifical fluids in organic synthesis have also been described. We hope that more green technologies using hydrogen peroxide in place of unsustainable ones could be worked out and applied.
出处
《有机化学》
SCIE
CAS
CSCD
北大核心
2011年第7期986-996,共11页
Chinese Journal of Organic Chemistry
基金
国家自然科学基金(No.20672088)
国家人力资源与社会保障部2010年度留学人员科技活动项目择优资助(优秀类项目)
成都理工大学优秀创新团队培育计划资助项目
关键词
绿色化学
过氧化氢
有机合成
进展
离子液体
氟相
超临界流体
环境保护
green chemistry
hydrogen peroxide
organic synthesis
progress
ionic liquid
fluorous phase
supercritical fluid
environment protection
