摘要
本文通过红外光谱、紫外及可见光谱对10种取代酞酰苯胺酸进行了研究。结果表明,配合物是通过羧酸根上羟基氧原子和酰胺羰基上氧原子配位成键,配合物均为八面体结构,但有不同程度变形,同时对它们的配位场参数10Dq,B等进行了计算.
The Complcxes of the type[Co(P-P)_2(H_2O)_2,P-P=2-Chlorophenyl,
3-chlorophenyl,2-bxomphenyl,3-bromophenyl,2-methylphenyl,
2-methoxyphenyl,4-cthoxyphenyl,2,4-dimethylphenyl,2,4-dinitrophenyl,2-nap
hthlphthalanic acids have been prepared and characterized by infrared and clec-
tronic spectra,The results show that coordination occurs through two oxygen at-
oms in amido and hydroxy of carboxylates.The complesxes are of octahedral struc-
ture only a small distortion prcscnt.Some of the lighand field parameters were cal-
culated.
出处
《西北大学学报（自然科学版）》
CAS
CSCD
1990年第3期39-42,共4页
Journal of Northwest University（Natural Science Edition）
关键词
酞酰苯胺酸
钴
配合物
光谱分析
Coordination compounds
Octahcdral
Structure
Infrared speetrophotometry.
