摘要
单硅酸的离解常数是表征其基本性质的重要数据,前人已有不少工作,但由于测定的方法和实验条件不同,所得数据很不一致。本实验室曾用“N’曲线法测得了单硅酸的各级离解常数,由于这些常数系在单硅酸到达多硅酸直至凝胶的过程中所测得,故和公认的单硅酸标准离解常数差别很大,只能称为胶凝离解常数。
On account of the ease of polymerization of silicic acid, it is difficult to make an accurate determination of dissociation constant of monosilicic acid. So the values obtained by different investigators usually do not agree. By use of trimethylsilylation process, standard dissociation constant of monosilicic acid has been determined. And by ion strength extrapolation, thermodynamic dissociation constant has also been determined. These constants are in good agreement with the accepted values.
出处
《无机化学学报》
SCIE
CAS
CSCD
北大核心
1990年第1期87-88,共2页
Chinese Journal of Inorganic Chemistry
基金
国家自然科学基金
关键词
单硅酸
离解常数
TMS-GC法
dissociation constant monosllicic acid trimethylsilylation-gas chromatography
