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N-烯丙基苯胺的合成研究 被引量:1

Study on the synthesis of N-allyl aniline
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摘要 以溴丙烯和苯胺为原料合成了N-烯丙基苯胺,通过IR和~1HNMR对化合物的组成和结构进行了表征,探讨了优化反应条件,该路线具有操作简便、反应快、收率高的特点。 N-allyl aniline was obtained from 3-propylene bromide and aniline.The chemical structure of product was characterized by IR and ~1HNMR.The optimum synthetic conditions of synthetic reactions were investigated. This method has many advantages,simplified operation,fast reaction state and high yield.
出处 《精细与专用化学品》 CAS 2011年第5期15-18,共4页 Fine and Specialty Chemicals
基金 甘肃省科技厅"科技支撑计划"(0804GKCA019)
关键词 烯丙基苯胺 溴丙烯 苯胺 合成 allyl aniline propylene bromide aniline synthesis
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  • 1Debalina Ghosh, Latibuddin Thander, Sanjay K Ghosh, et al Sequential Aza-claisen rearrangement and ring-closing metath esis as a route to 1-benzazepine derivatives [J]. SynLett 2008 19: 3011-3015.
  • 2Danielle M. Sehultz, John P. Wolfe. Synthesis of polycyclic nitrogen heterocycles via alkene aminopalladation/carbopalladation cascade reactions [J]. Org Lett, 2010, 12 (5) : 1028- 1031.
  • 3Laksmikanta Adak, Kalicharan Chattopadhyay, Brindaban C Ranu. Palladium nanoparticle-catalyzed C-N bond formation. A highly regio- and stereosetective allylic amination by allyl acetates[J]. Org Chem, 2009, 74(10): 3982 -3985.
  • 4Gaku Hattori, Ken Sakata, Hiroshi Matsuzawa, et al. Copper-catalyzed enantooselective propargylic amination of propargylic esters with amines: copper allenylidene complexes as key intermediates[J].J Amer Chem Soc, 2010, 132(30): 10592 -10608.
  • 5Israel Gonzalez, Iria Bellas, Ana Souto, et al. Microwaveassisted aza cope rearrangement of N-allyl anilines [J]. Tetrahedron Letters 2008, 49 (12): 2002-2004.
  • 6Samir Zard, Fir Sur-Yvette, Alejandro Cordero Vargas, et al. Method of preparing benzazeplnes and derivatives thereof [P]. US20070185323,2007.
  • 7Kimura Masanari Futamata Makoto, Shibata kazufumi, et al. Pd · Et3B-catalyzed alkylation of amines with allylic alcohols [J]. Chem Commun. 2003,2: 234-235.
  • 8Ozawa Fumiyuki, Okamoto Hideyuki, Kawagishi Seiji, et al. (n-Ally/) palladium complexes bearing diphosphinidenecyclobutene ligands (DPCB): highly active catalysts for direct conversion of allylie alcohols[J]. J Amer Chem Soc, 2002, 124 (37): 10968-10969.
  • 9Barluenga Jose, Perez-Prieto Julia, Asensio Gregorio. Catalytic aminomercuration of olefins in a tandem aminomereurationdeoxymercuration; one-step synthesis of secondary n-arylallylamines from allylaleohols [J]. Tetrahedron. 1990, 46 (7) : 2453-2460.
  • 10Lothar W Bieber, Rosenildo C da Costa, Margarete F da Silva. Reductive alkylation of nitrobenzene promoted by zinc and tin in protic solvents [J].Tetrahedron Letters, 2000, 41 (25) : 4827-4830.

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