摘要
本文首先概述了烯烃或醇经Koch羰基化反应合成羧酸的几种主要催化体系及其反应工艺的现状和优缺点,报道了国内外目前研究的几种不同催化剂体系中Koch羰基化反应的反应机理,提出了开发有关Koch羰基化反应合成含氧化合物研究的重要性、发展前景和实用价值,从而对唤起我国开发在温和条件下的Koch羰基化和Koch羰基化催化剂的固相化研究工作起到一定的影响。
In this paper, some important catalytic systems and advantages of shortcomings of techniques applied to car-boxylic acids synthesis from olefin or alcohol by Koch carbonylation were summarized, and the advances of their reactive mechanisms in the world were discussed. Also the importance, developing prospect and practical value of oxide-contained compounds by Koch carbonylation were presented. It will surely arouse researchers' interest to develop Koch carbonylation in mild reaction condition and solid phase catalysts in our country.
出处
《化工进展》
EI
CAS
CSCD
1999年第6期23-26,36,共5页
Chemical Industry and Engineering Progress
基金
国家自然科学基金资助项目
关键词
Koch羰基化
氧化物
羰酸
合成
Koch Carbonylation, Oxide-compound, Reaction, Mechanism, Carboxylic Acid
