摘要
以自制的类双酚化合物与二卤单体反应，以及类双酚与对氯苯腈反应合成了 ３ 种模型化合物；通过对模型化合物的结构分析，证实了该新型类双酚单体中 Ｎ Ｈ 参与亲核取代反应，形成了 Ｃ Ｎ 相连而非 Ｃ Ｏ 相连结构，进而提出了类双酚单体经亲核取代反应合成聚芳醚的反应机理．
A novel phenol\|like compound 4\|phenyl\|2,3\|phthalazine\|1\|one and the bisphenol\|like monomer 4\|(4\|hydroxylphenyl)\|2,3\| phthalazine\|1\|one were successfully used to synthesize three model compounds to prove the polymerization mechanism. The structure of the model compounds implied the C N coupling reaction. By analysis of the model reaction, the polymerization mechanism of the monomer is put forward.
出处
《大连理工大学学报》
CAS
CSCD
北大核心
1999年第5期629-634,共6页
Journal of Dalian University of Technology
基金
国家"九五"重点科技攻关项目
关键词
聚芳醚
聚合
二氮杂萘联苯型
polymerization mechanism/phenol\|like compound
bisphenol\|like compound
model compound
