摘要
针对钻井废水悬浮物和ＣＯＤ含量高的污染特征，对其酸化中和预处理的可行性进行了实验研究，并对其作用机理进行了探讨。以浓Ｈ２ＳＯ４ 调节废水的ｐＨ值至１５，加入石灰乳中和使ｐＨ为９，可使ＣＯＤｃｒ的去除率达到５０％ ，悬浮物的去除率达到８０％ 。预处理可在废水池内进行，给下一步利用装置进行混凝处理创造了条件。钻井废水中粘土颗粒稳定的主要原因是颗粒物连有强亲水基团：－ Ｏ－ 、－ ＳＯ３－ 和－ ＣＯＯ－ 。在酸性条件下，这些基团以－ ＯＨ、－ ＳＯ３Ｈ和－ＣＯＯＨ形式存在，破坏了负离子稳定体系。
Be directed towards the character of high content of suspended solids and COD,lab work has been done on the possibility of acidizing and pre process of drilling waste water,also,its mechanism has been discussed.Adjust the pH of drilling wastewater by high content H 2SO 4,then put the lime emulsion into it to make the pH be 9.0,the COD elimination rate will be 50%,and the suspended solids elimination rate will be above 80%.This process can be done in wastewater tank,proving the condition of using the coagulant for the next step.The main reson why the stability of the clay solids is they have hydrophilic group:-O -、-SO 3 - and COO -,but under the acid condition they become—OH,SO 3H,-COOH,then the ionic stability is broken,the clay particles subside.
出处
《重庆环境科学》
1999年第5期45-46,57,共3页
Chongqing Environmental Science
关键词
钻井废水
酸化
中和预处理
机理
废水处理
石油
Drilling waster water,Acidizing neutralization,Pre process,Mechanism.
