摘要
本实验应用四酸(硝酸,盐酸,氢氟酸,高氯酸)混合溶矿,电感耦合等离子体原子发射光谱法(ICP-AES)同时测定了铁矿石、铜矿石、铅矿石、锌矿石及多金属矿石样品中Al、Fe、Cu、Pb、Zn、Ca、Mg、K、Na、Sb、Mn、Ti、Li、Be、Cd、Ag、Co、Ni、Sr、V、Mo和S 22个元素量。实验确定了方法的分解条件以及测定元素的检出限及干扰条件。用国家一级标准物质GBW07162(多金属贫矿石)和GBW07163(多金属矿石)进行精密度实验,统计数据显示,结果精密度(RSD)和准确度(RE)都小于10%,而且大多数元素的精密度和准确度在5%范围内。通过标准物质进行方法验证,非单矿物或精矿的一般硫化物矿石的检测结果基本都在标准值的范围内,符合地质矿产开发的要求。本方法具有同时测定元素多、线性范围宽、检出限低等优点,实际使用性强,结果满意。
This paper presents a method to determine 22 elements of Al、Fe、Cu、Pb、Zn、Ca、Mg、K、Na、Sb、Mn、Ti、Li、Be、Cd、Ag、Co、Ni、Sr、V、Mo and S in sulphide ores,including ironstone,copper ore,lead and zinc ore and multi-metal ore by Inductively Coupled Plasma Atomic Emission Spectrometry（ICP-AES）using nitric acid,hydrochloric acid,hydrofluoric acid and perchloride acid for sample digestion.The techniques for sample dissolution,detection limits and spectrum interference of coexisting elements were studied,and the optimal analytical wavelengths were selected.The accuracy and precision of this method were examined by analyzing different reference materials.The results were in a good agreement with the certified values.The proposed method has been successfully applied for routine lab analysis.
出处
《矿物岩石地球化学通报》
CAS
CSCD
北大核心
2011年第1期65-72,共8页
Bulletin of Mineralogy, Petrology and Geochemistry
基金
国家地质实验测试中心所长基金资助项目(121235068101801)
关键词
铁、铜、锌、铅等硫化物矿石
电感耦合等离子体光谱
四酸熔矿
sulphide ores with iron
copper
zinc
lead
inductively coupled Plasma Atomic Emission Spectrometry（ICP-AES）
four acids digestion
