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三(2-甲基-2-苯基丙基)锡羧酸酯的合成、结构表征和生物活性 被引量:12

Preparation, Structure Characterization and Bioassay of Tris(2 methyl 2 phenylpropyl)tin Carboxylates
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摘要 Fifteen tris(2 dimethyl 2 phenylpropyl)tin carboxylates were synthesized and characterized by IR and 1H NMR. The results showed that these compounds may be four coordinated and there are a linear relationship between Δν CO 2 and the Hammett constants ( σ) of the para substituents of the corresponding substituted benzoates. The bioasay tests show that neophyltin derivatives have a good acaricidal activity and may provide an acaricide for the better activity and economy. Fifteen tris(2 dimethyl 2 phenylpropyl)tin carboxylates were synthesized and characterized by IR and 1H NMR. The results showed that these compounds may be four coordinated and there are a linear relationship between Δν CO 2 and the Hammett constants ( σ) of the para substituents of the corresponding substituted benzoates. The bioasay tests show that neophyltin derivatives have a good acaricidal activity and may provide an acaricide for the better activity and economy.
出处 《高等学校化学学报》 SCIE EI CAS CSCD 北大核心 1999年第11期1743-1745,共3页 Chemical Journal of Chinese Universities
关键词 苯丁锡 羧酸酯 锡羧酸酯 有机锡 杀螨剂 Neophyltin, Carboxylate, Structure characterization, Bioassay, Acaricidal activity
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参考文献5

  • 1刘宝殿 宁志刚 等.-[J].高等学校化学学报,1995,16:84-84.
  • 2谢庆兰 林森 等.-[J].高等学校化学学报,1994,15:1477-1477.
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  • 4谢庆兰,高等学校化学学报,1994年,15卷,1477页
  • 5Xie Qinglan,Chemistry and Technology of Silicon and Tin,1992年,521页

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