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MoO_3在Al_2O_3薄膜表面扩散的研究 被引量:2

Study of MoO_3 Surface Diffusion on the A1_2O_3 Film
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摘要 A flat and compact Al2O3 film of 20urn in thickness was prepared on the substrate of Si wafer by magnetic controlled sputtering Al reaction with O2 in Ar. A small amount of MoO3 was va- porized in vacuum and deposited onto a slot in a covering film on the surface of A12O3 film. The samples were heated in dry or wet N2, O2 and air respectively, characterized by TRSRF, AES, XPS, XRD and SEM to study the surface diffusion of MoO3 on the A12O3 film. The results show that MoO3 can diffuse on the surface of Al2O3 film by heating the samples at 573K or 673K. The diffusion rate increases with the heating temperature. moisture can accelerate the diffusion rate of MoO3 on the surface of Al2O3. A flat and compact Al2_O3 film of 20urn in thickness was prepared on the substrate of Si wafer by magnetic controlled sputtering Al reaction with O2 in Ar. A small amount of MoO3 was va- porized in vacuum and deposited onto a slot in a covering film on the surface of A12O3 film. The samples were heated in dry or wet N2, O2 and air respectively, characterized by TRSRF, AES, XPS, XRD and SEM to study the surface diffusion of MoO3 on the A12O3 film. The results show that MoO_3 can diffuse on the surface of Al_2O_3 film by heating the samples at 573K or 673K. The diffusion rate increases with the heating temperature. moisture can accelerate the diffusion rate of MoO_3 on the surface of Al_2O_3.
出处 《物理化学学报》 SCIE CAS CSCD 北大核心 1999年第8期684-687,共4页 Acta Physico-Chimica Sinica
基金 国家自然科学基金!(29733080) 攀登计划基金资助项目
关键词 表面扩散 扩散 三氧化钼 氧化铝 Oxide, Surface diffusion, AES, TRSRF
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  • 1谢有畅,Adv Catal,1990年,37卷,1页
  • 2桂琳琳,中国科学.B,1985年,6期,509页
  • 3刘英骏,催化学报,1982年,3卷,4期,262页
  • 4唐有祺,自然科学进展,1994年,4卷,6期,642页

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  • 1许越.催化剂设计与制备工艺[M].北京:化学工业出版社,2004.
  • 2Sejidov F T,Mansoori Y,Goodarzi N. Esterification reaction using solid heterogeneous acid catalysts under solvent-less condition[ J ]. Journal of Molecular Catalysis A : Chemical, 2005,240 ( 1/2 ) : 186 - 190.
  • 3E1-Wahab M M M,Said A A. Phosphomolybdic acidsupported on silica gel and promoted with alkali metal ions as catalysts for the esterificatioo of acetic acid by ethanol [ J ]. Journal of Molecular Catalysis A : Chemical,2005,240 ( 1/2 ) : 109 - 118.
  • 4Jenny B R, Pandurangan A. Catalytic application of Al-MCM-41 in the esterification of acetic acid with various alcohols [ J ]. Applied Catalysis A : General ,2005,288 ( 1/2 ) :25 - 33.
  • 5F|ores 0 G M, Ha S. Activity and stability studies of MoO2 catalyst for the partial oxidation of gasoline [ J ]. Applied Catalysis A: General,2009,352 ( 1/2 ) : 124 - 132.
  • 6Fujikawa T. Highly active HDS catalyst for producing ultra-low sulfur diesel Fuels[J]. Topics in Catalysis,2009,52(6/7) :872 -879.
  • 7Rodriguez-Gattorno G, Martinez-Hernandez A, Aleman-Vazquez L O, et al. Structural and thermal study of carbon-modified molybdenum sub-oxide catalysts [J]. Applied Catalysis A: General ,2007,321 ( 2 ) : 117 - 124.
  • 8Chandorkar J G, Umbarkar S B, Rode C V,et al. Synthesis of tinidazole by condensation-oxidation sequence using MoO3/SiO2 bifunctional catalyst [ J ]. Catalysis Communications, 2007, 8 (10) : 1550 - 1555.
  • 9Said A A, Abd E1-Wahab M M M. Surface properties and catalytic behavior of MoO3/SiO2 in esterification of acetic acid with ethanol[ J ]. Journal of Chemical Technology and Biotechnology, 2006,81 (3) :329 -335.
  • 10Said A A. Gas phase esterification of acetic acid with ethanol over MoO3 supported on A1PO4 and the effect of modification with phosphomolybdic acid and Ce^4+ ions [ J ]. Journal of Chemical Technology and Biotechnology ,2003,78 (7) :733 - 742.

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