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3,3′-二羟基-4,4′-联苯二胺的合成与表征

Synthesis and Characterization of 3,3′-Dihydroxybenzidine
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摘要 以3,3′-二甲氧基联苯二胺盐酸盐为原料,以氢碘酸为溶剂,在回流状态下发生碘代反应,再经乙酸钠中和合成了3,3′-二羟基-4,4′-联苯二胺(DHB),其结构和纯度分别用红外光谱、核磁氢谱、核磁碳谱、元素分析和高压液相色谱加以表征. 3,3′-dihydroxybenzidine was synthesized through a two-step reaction,the iodination of raw materials and the neutralization reaction with sodium acetate.The structure and the purity of final product were characterized by FT-IR spectroscopy,1H-NMR and 13C-NMR,elemental analysis and HPLC respectively.
作者 蒋少华 段改改 刘昆明 李娟华 胡晓婺 侯豪情
机构地区 江西师范大学化学化工学院
出处 《江西师范大学学报（自然科学版）》 CAS 北大核心 2010年第2期157-159,共3页 Journal of Jiangxi Normal University(Natural Science Edition)
基金 教育部高等学校科技创新工程重大项目培育资金(707038) 江西省教育厅重大科技项目(2006-109 2007-103) 2009年江西省研究生创新基金资助项目
关键词 3 3′-二羟基-4 4′-联苯二胺 3 3′-二甲氧基联苯二胺盐酸盐 合成 表征 3 3′-dihydroxybenzidine 3 3′-dimethoxybenzidine dihydrochloride synthesis characterization
分类号 O625.6 [理学—有机化学]
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参考文献9

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共引文献27

江西师范大学学报（自然科学版）
2010年 第2期

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