摘要
以煤油为油相，以Ｓｐａｎ８０与Ｔｗｅｎ６０为复合乳化剂，对ＡＩＢＮ引发丙烯酰胺反相微乳液聚合宏观动力学进行了研究，得到Ｒｐ∝［Ｍ］１．５０［Ｉ］０．６９［Ｅ］１．５６，聚合表观活化能为６８．８ＫＪ／ｍｏｌ，并且发现聚合过程中出现短暂的恒速期。同时对ＫＰＳ引发聚合体系亦进行了比较考察。最后对乳胶粒作了初步讨论，发现每个粒子内所含的大分子链数量很少。
The inverse microemulsion polymerization of acrylamide initiated by AIBN in the systems composed of kerosine,Span80-Tween60 and water has been investigated. A short period of constant rate was observed during polymerization. It was indicated from the epperiments that the polymerization kinetics can be expressed as R p ∝ 1.50 0.69 1.56 . And the apparent active energy of such polymerization is 68.8kJ/mol. The polymerization initiated by KPS was also discussed. The numble of polymer chains per particle obtained from this study were far lower than those macroemulsion polymerization.
出处
《化学反应工程与工艺》
EI
CAS
CSCD
北大核心
1999年第1期13-18,共6页
Chemical Reaction Engineering and Technology
