摘要
综述了水溶性金属卟啉作为催化剂应用于均相或非均相的催化反应的研究进展,重点介绍了水溶性金属卟啉在水或水与有机溶剂混合介质中催化底物氧化反应的催化性能,其中包括烷烃的羟基化,烯烃的环氧化,含氧、含硫及含氮化合物的氧化反应.另外水溶性金属卟啉还可用于催化Suzuki-Miyaura反应、氧化偶联反应、C=C氧化断裂反应等.水溶性金属卟啉催化剂具有水溶性、催化效率高、反应条件温和等优点,因此将在催化反应特别是氧化反应中得到更广泛的应用.
The latest applications of water-soluble metalloporphyrins as catalysts in catalytic homogeneous or heterogeneous reactions are reviewed,focusing on the catalytic activities of water-soluble metallopor-phyrins-catalyzed oxidation reactions in water or the mixed media of water and organic solvents,including the oxidation of alkanes,epoxidation of alkenes,the oxidation of compounds containing oxygen,sulfur and nitrogen.Water-soluble metalloporphyrins could also be used in other catalytic reactions,such as Suzuki-Miyaura reaction,oxidative coupling reaction,oxidative cleavage of C=C double bond etc.Water-soluble metalloporphyrins as catalysts will be widely used in catalytic reactions,especially in oxidations for its water solubility,effective activity,and under mild conditions.
出处
《有机化学》
SCIE
CAS
CSCD
北大核心
2010年第11期1605-1614,共10页
Chinese Journal of Organic Chemistry
基金
国家自然科学基金(Nos.21036009
20976203)
广东省高等学校高层次人才项目
中国博士后科学基金(No.20080440792)资助项目
关键词
水溶性金属卟啉
催化氧化
仿生催化
water-soluble metalloporphyrin
catalytic oxidation
biomimetic catalysis
