摘要
研究了Ｔｍ（０．１）Ｙｂ（１０９）氟氧化物玻璃在８００ｎｍ半导体激光激发下的间接上转换敏化发光现象．通过Ｔｍ（０１）Ｙｂ（３）：ＺＢＬＡＮ玻璃和Ｔｍ（０１）Ｙｂ（１０９）氟氧化物玻璃中Ｔｍ３＋离子上转换发光的比较研究，发现在间接上转换敏化的情况下，Ｔｍ（０１）Ｙｂ（１０９）氟氧化物玻璃中Ｔｍ３＋离子的上转换发光极大地增强，超过了Ｔｍ（０１）Ｙｂ（３）：ＺＢＬＡＮ玻璃的水平．说明在此类上转换激发机制下，有着较高的稀土溶解度和较大的截止声子能量的材料可能有最佳的上转换效率，它将可能有比目前最好的ＺＢＬＡＮ材料高许多的上转换发光强度，这对于上转换研究迅速走向实际应用有重大的意义．目前尚未见到其他类似研究报道．
Abstract In this paper we study the indirect upconversion
sensitization luminescence of Tm(0.1)Yb(10 9):oxyfluoride glass induced by 800nm diode
laser. Through the comparison between Tm(0 1)Yb(10 9):oxyfluoride and Tm(0 1)Yb(3):ZBLAN
glasses we found that the upconversion luminescence intensity of Tm(0.1)Yb(10.9):oxyfluoride
glass was greatly enhanced and exceeded the level of Tm(0.1)Yb(3):ZBLAN glass under the
condition of indirect upconversion sensitization. The results illustrated that under this kind of
upconversion mechanism, it is possible to find some kind of material which has higher rare
earth doped concentration and cut off phonon energy, thus showing much higher upconversion
efficiency than ZBLAN. This work and the results obtained will be helpful to promote the
upconversion research to practical application. To our best knowledge, there have not been
similar works published domestically and a broad.
出处
《物理学报》
SCIE
EI
CAS
CSCD
北大核心
1999年第5期948-954,共7页
Acta Physica Sinica
基金
国家自然科学基金
国家教育部博士点基金
