期刊文献+

海水中二甲基硫的光化学氧化研究 被引量:4

Studies on Photochemistry of Dimethylsulfide in Seawater
在线阅读 下载PDF
导出
摘要 二甲基硫(DMS)是海洋中最重要的挥发性生源硫化物,其在大气中的氧化产物会对全球气候变化和酸雨的形成产生重要影响。海水中DMS的光化学氧化,作为一个重要的去除途径,是控制海水中DMS浓度的重要因素。这个复杂的动态过程会受到光照、深度、海水中的溶解无机和有机物这些物理、化学因素的影响。根据光化学降解在DMS的全球生物地球化学循环中的重要作用,作者综述了国际海洋科学工作者近20年来在海水中DMS光化学研究方面的最新进展。 Dimethylsulfide (DMS) is the dominant volatile biogenic sulfur compound emanating from the ocean, which plays an important role in Earth's climate change and the environmental acidification due to its oxidation products in the atmosphere. Photolysis is an important removal process for upper ocean DMS and has a potential influence on DMS concentrations. This dynamic process might depend on the quantity and quality of solar radiation, dissolved inorganic/organic concentrations and quality, as well as the seawater depth. Considering the potential importance of photochemical processes in the DMS global biogeochemical cycle, an increasing amount of research has been performed in the photo-degradation processes which control the removal of DMS in marine environment.
出处 《中国海洋大学学报(自然科学版)》 CAS CSCD 北大核心 2010年第10期79-84,共6页 Periodical of Ocean University of China
基金 国家杰出青年科学基金项目(40525017) 国家自然科学基金项目(40476034) 山东省科技攻关计划项目(2006GG2205024) 教育部"长江学者"奖励计划 山东省‘泰山学者’建设工程专项经费资助
关键词 二甲基硫 光化学降解 光敏剂 海水 dimethylsulfide photodegradation photosensitizer seawater
  • 相关文献

参考文献1

二级参考文献35

  • 1[1]Andreae M O.1980.Dimethylsulfoxide in marine and fresh waters.Limnol Oceanogr,24:440~452
  • 2[2]Andreae M O.1990.Ocean-atmosphere interactions in the global biogeochemical sulfur cycle.Mar Chem,30:1~29
  • 3[3]Andreae M O,Barnard W R.1983.Determination of trace quantities of dimethylsulfide in aqueous solutions.Anal Chem,55:608~612
  • 4[4]Bates T S,Charlson R J,Gammon R H.1987.Evidence for the climatic role of marine biogenic sulphur.Nature,329:319~321
  • 5[5]Bates T S,Cline J D,Gammon R H,et al.1987.Regional and seasonal variations in the flux of oceanic dimethylsulfide to the atmosphere.J Geophys Res,92:2 930~2 938
  • 6[6]Bors W,Saran M,Lengfelder E,et al.1974.Relevance of the superoxide anion radical in biological systems.Curr Top Radiat Res Q,9:247~309
  • 7[7]Brimblecombe P,Shooter D.1986.Photo-oxidation of dimethylsulphide in aqueous solution.Mar Chem,19:343~353
  • 8[8]Brugger A,Slezak D,Obernosterer I,et al.1998.Photolysis of dimethylsulfide in the northern Adriatic Sea:dependence on substrate concentration,irradiance and DOC concentration.Mar Chem,59:321~331
  • 9[9]Charlson R J,Lovelock J E,Andreae M O,et al.1987.Oceanic phytoplankton,atmospheric sulphur,cloud albedo,and climate.Nature,326:655~661
  • 10[10]Cooper W J,Zika R G.1983.Photochemical formation of hydrogen peroxide in surface and ground waters exposed to sunlight.Science,220:711~712

共引文献3

同被引文献68

引证文献4

二级引证文献15

相关作者

内容加载中请稍等...

相关机构

内容加载中请稍等...

相关主题

内容加载中请稍等...

浏览历史

内容加载中请稍等...
;
使用帮助 返回顶部