摘要
以异烟酸和溴代十二烷为原料合成液晶基元异烟酸十二烷基酯,以水杨醛和邻氨基苯酚为原料来制各希夫碱,将希夫碱与异烟酸酯同时与过渡金属配位,透射电镜形态观测到10～60m左右的线状形态的纳米胶束。并利用红外光谱,紫外可见吸收光谱等手段对其结构和性质进行了表征。
In the first, pyridine-4-carboxylic acid reacted with dodecyl bromide to give liquid crystal unit dodecyl pyridine-4-carboxylate, which was further treated with transition metal ion to form the coordination compound. The nano-micelle which was 10-60 nm of column morphology observed by TEM was formed. The structure and properties of the complex were characterized by Fourier transform infrared spectroscopy （FTIR） and ultraviolet spectrum （UV）.
出处
《广州化学》
CAS
2010年第3期16-20,56,共6页
Guangzhou Chemistry
关键词
异烟酸十二烷基酯
液晶基元:过渡金属
自组装
纳米胶束
dodecyl pyridine-4-carboxylate
liquid crystal unit
transition metal
self-assembly
nano-micelle
